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过程工程学报 ›› 2021, Vol. 21 ›› Issue (12): 1481-1490.DOI: 10.12034/j.issn.1009-606X.221010

• 过程与工艺 • 上一篇    下一篇

外加磁场对电渣锭洁净度的影响研究

施晓芳1, 朱春丽1, 徐涛2, 常立忠1*
  

  1. 1. 安徽工业大学冶金工程学院,安徽 马鞍山 243002 2. 安徽富凯特材有限公司,安徽 绩溪 245300
  • 收稿日期:2021-01-08 修回日期:2021-03-05 出版日期:2021-12-28 发布日期:2022-03-28
  • 通讯作者: 常立忠 clz1997@163.com
  • 作者简介:施晓芳(1978-),女,浙江省永康市人,博士,副教授,钢铁冶金专业,E-mail: shixiaofang602@163.com;常立忠,通讯联系人,E-mail: clz1997@163.com.
  • 基金资助:
    偏心结晶器-电磁调控协同作用下电渣重熔双金属复合轧辊 的研究;电渣重熔过程增氧机理研究;复合电源耦合作用下电渣锭凝固组织细化机理研究

Effect of external magnetic field on cleanliness of electroslag ingot

Xiaofang SHI1,  Chunli ZHU1,  Tao XU2,  Lizhong CHANG1*   

  1. 1. School of Metallurgy Engineering, Anhui University of Technology, Ma'anshan, Anhui 243002, China 2. Anhui Fukai Special Material Co., Ltd., Jixi, Anhui 245300, China
  • Received:2021-01-08 Revised:2021-03-05 Online:2021-12-28 Published:2022-03-28
  • Contact: Li-zhong -CHANG clz1997@163.com

摘要: 为进一步去除电渣锭中的大颗粒夹杂物,设计了带电磁搅拌的电渣重熔炉,研究了外加磁场及不同的电参数变化对电渣锭洁净度的影响,采用氧氮分析仪分析了气体含量的变化,采用扫描电镜分析了夹杂物形貌、组成、尺寸的变化。结果表明,不论是否施加磁场,电渣重熔后电渣锭中的氧含量明显增加,从自耗电极中的0.0007%增加最高至0.0052%,增幅高达7倍;氮含量略微下降。但夹杂物类型基本不变,主要由氧化铝、硫化锰、硫化锰?氧化物复合夹杂及氧化物等组成,且以氧化铝为主。外加磁场重熔以后,电极中最大夹杂物的直径从89.6 μm降为电渣锭中的12.1 μm (1.1 kA/108 Gs),小颗粒夹杂物所占的比例增加,大颗粒夹杂物的数量减少。但过高的电磁力会降低夹杂物的去除效果,当采用1.5 kA/108 Gs的工艺参数重熔时,最大的夹杂物尺寸为30.6 μm,超过了未施加磁场的电渣锭中的夹杂物。电渣重熔后氧含量增加主要受空气污染及渣系中不稳定氧化物的分解,而外加磁场后产生的电磁力增大了渣?金接触面积,从而吸收了电极中的大颗粒夹杂物。

关键词: 电渣重熔, 磁场, 夹杂物, 轴承钢,

Abstract: In order to further remove the large inclusions, an electroslag remelting furnace with electromagnetic stirring is designed and the effects of external magnetic field and different electrical parameters on the cleanliness of electroslag ingot are studied. The gas content is analyzed by oxygen and nitrogen analyzer, and the morphology, composition and size of inclusions are observed and analyzed by scanning electron microscope. It is found that the oxygen content in ESR ingot increases obviously after electroslag remelting whether the external magnetic field is applied or not, but the nitrogen content decreased slightly. The oxygen content in consumable electrode increased from 0.0007% to 0.0052%, and the growth rate is as high as 7 times. However, the types of inclusions are basically unchanged, which are mainly composed of alumina, manganese sulfide, manganese sulfide oxide composite inclusions and oxides, among which alumina is the most. After remelting with external magnetic field, the diameter of the largest inclusion in the consumable electrode decreased from 89.6 μm to 12.1 μm in ESR ingot (1.1 kA/108 Gs), the proportion of small inclusions increases and the number of large inclusions decreases. However, excessive electromagnetic force is not conducive to the removal of large inclusions. When the remelting current is 1.5 kA and the magnetic induction is 108 Gs, the electromagnetic force is the largest, and the maximum diameter of inclusions is up to 30.6 μm which is larger than that in electroslag ingot without magnetic field. The increase of oxygen content after electroslag remelting is caused by air pollution and unstable oxides in slag. The electromagnetic force generated by external magnetic field increases the contact area between slag and metal, thus absorbing large inclusion.

Key words: electroslag remelting, magnetic field, inclusion, bearing steel, oxygen