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›› 2006, Vol. 6 ›› Issue (3): 499-502.

• 材料工程专栏 • 上一篇    下一篇

晶化温度对介孔材料SBA-15结构与形貌的影响

周丽绘,张利中,刘洪来   

  1. 华东理工大学化学系
  • 出版日期:2006-06-20 发布日期:2006-06-20

Effect of Crystallization Temperature on Structure and Morphology of Mesoporous SBA-15

ZHOU Li-hui,ZHANG Li-zhong,LIU Hong-lai   

  1. Department of Chemistry, East China University of Science and Technology
  • Online:2006-06-20 Published:2006-06-20

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被引次数

42

摘要： 以P123嵌段共聚物表面活性剂为模板剂，在不同晶化温度下合成了不同孔径和比表面积的六方相介孔氧化硅SBA-15，通过XRD, SEM, N2吸附-脱附及TEM等手段系统考察了不同晶化温度对SBA-15晶胞参数、比表面积、孔径及形貌的影响，得到反应最佳晶化温度为120℃. 随着晶化温度的升高，SBA-15的孔径增大，比表面积下降，团聚体颗粒打开形成散落短棒状. 同时还对温度影响SBA-15结构和形貌的机理进行了探讨.

关键词: P123, 合成, 晶化温度, 介孔氧化硅SBA-15

Abstract: Highly ordered hexagonal mesoporous SBA-15 with different pore sizes and BET surface areas was prepared under different crystallization temperatures, using nonionic triblock P123 as template. By means of XRD, SEM, N2 adsorption-desorption and TEM, the effects of crystallization temperature on morphology, surface area and pore size of SBA-15 were investigated. The results indicate that the best crystallization temperature is about 120℃. With increasing of crystallization temperature, the pore size of SBA-15 is increased and BET surface area decreased. When the crystallization temperature is 140℃ or higher, SEM images reveal that the morphology of SBA-15 is changed from "wheat-like" agglomerate particles to "banana-like" short rods. These results are discussed further in terms of the synthesis mechanism of SBA-15 and structure characteristics of P123 surfactant.

Key words: P123 surfactant, synthesis, crystallization temperature, mesoporous SBA-15