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›› 2010, Vol. 10 ›› Issue (1): 115-120.

• 过程与工艺 • 上一篇    下一篇

Enhanced Formation of HCFC141b Hydrate with HCFC141b-in-water Emulsion

周锡堂 关进安 梁德青   

  1. 中国科学院可再生能源与天然气水合物重点实验室 中国科学院可再生能源与天然气水合物重点实验室
  • 收稿日期:2009-06-08 修回日期:2009-10-15 出版日期:2010-02-20 发布日期:2010-02-20
  • 通讯作者: 周锡堂

Enhanced Formation of HCFC141b Hydrate with HCFC141b-in-water Emulsion

ZHOU Xi-tang GUAN Jin-an LIANG De-qing   

  1. Guangzhou Institute of Energy Conversion, Guangzhou NGH Center, CAS Guangzhou Institute of Energy Conversion, Guangzhou NGH Center, CAS Key Laboratory of Renewable Energy and Gas Hydrate, CAS
  • Received:2009-06-08 Revised:2009-10-15 Online:2010-02-20 Published:2010-02-20
  • Contact: ZHOU Xi-tang

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被引次数

5

摘要： Enhanced formation of HCFC141b hydrate was studied with HCFC141b emulsion before the hydrate formation. Tergitol TMN6 was selected as emulgator, HCFC141b and water were introduced into an airtight emulsifier at the molecular ratio of 17:1 and emulsified at the temperature of 14℃ under the stirring speed of 4000~6400 r/min. And HCFC141b hydrate formed and decomposed with the change of programmed temperature. The experimental results showed that with the new method HCFC141b hydrate began to form in the time of 30 min (in glycol-water bath) or 100 min (in air bath) even in static state, and under the same condition with conventional method (non-emulsion) the hydrate could not form, at least it difficultly formed. And in dynamic state HCFC141b emulsion formed hydrate in 20 min earlier than the mixed liquid did, liquid from hydrate decomposition was emulsified after brief stirring, and formed hydrate again more easily than the brand-new emulsion.

关键词: enhance, HCFC141b hydrate, emulsion, formation, decomposition

Abstract: Enhanced formation of HCFC141b hydrate was studied with HCFC141b emulsion before the hydrate formation. Tergitol TMN6 was selected as emulgator, HCFC141b and water were introduced into an airtight emulsifier at the molecular ratio of 17:1 and emulsified at the temperature of 14℃ under the stirring speed of 4000~6400 r/min. And HCFC141b hydrate formed and decomposed with the change of programmed temperature. The experimental results showed that with the new method HCFC141b hydrate began to form in the time of 30 min (in glycol-water bath) or 100 min (in air bath) even in static state, and under the same condition with conventional method (non-emulsion) the hydrate could not form, at least it difficultly formed. And in dynamic state HCFC141b emulsion formed hydrate in 20 min earlier than the mixed liquid did, liquid from hydrate decomposition was emulsified after brief stirring, and formed hydrate again more easily than the brand-new emulsion.

Key words: enhance, HCFC141b hydrate, emulsion, formation, decomposition

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