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›› 2011, Vol. 11 ›› Issue (2): 329-335.

• 材料工程专栏 • 上一篇    下一篇

离子交换膜面电阻的测定及其影响因素

赵西云 王倩 石绍渊 丛威   

  1. 中国科学院过程工程研究所生化工程国家重点实验室 中国科学院过程工程研究所生化工程国家重点实验室 中国科学院过程工程研究所 中国科学院过程工程研究所生化工程国家重点实验室
  • 收稿日期:2011-03-08 修回日期:2011-03-28 出版日期:2011-04-20 发布日期:2011-04-20
  • 通讯作者: 赵西云

Measurement of Area Resistance of Ion-exchange Membrane and Its Influential Factors

ZHAO Xi-yun ZHANG Li-ye, SHI SHAO-yuan CONG Wei   

  1. State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences State Key Lab. Biochem. Eng., Institute of Process Engineering, Chinese Academy of Science Institute of Process Engineering, China Academy of Sciences State Key Lab. Biochem. Eng., Inst. Process Eng., CAS
  • Received:2011-03-08 Revised:2011-03-28 Online:2011-04-20 Published:2011-04-20
  • Contact: ZHAO Xi-yun

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被引次数

4

摘要： 采用自行设计的交流电法测定装置及优化的测定条件对几种离子交换膜的面电阻(Ra)进行了测定，并考察了其影响因素. 结果表明，优化的测定条件为电导池电极间距10 mm、极室直径20 mm，测定电压频率为100.0 kHz、电压为100 mV. JAM和JCM系列膜的Ra与含水量呈负相关，阴膜RXAM和阳膜RXCM的Ra受溶液中反离子种类影响较大，受同离子影响较小，而双极膜RXBM的Ra则同时受溶液中阴离子和阳离子种类的影响；当溶液浓度低于0.5 mol/L时，Ra随溶液浓度升高而明显降低，高于1.0 mol/L以上时较稳定.

关键词: 离子交换膜, 面电阻, 测定方法, 影响因素

Abstract: Area resistance (Ra) of several kinds of ion-exchange membrane (IEM) is determined using alternating current method by self-designed device and optimized measuring conditions. Influential factors of Ra value are also studied. The distance between the electrodes of conductivity cell is 10 mm and the chamber diameter 20 mm. The frequency of alternating current is 100.0 kHz and voltage 100 mV. For the membranes of JAM and JCM series, Ra shows negative correlation with water content. Ra of anion membrane RXAM-1003 and cation membrane RXCM-1003 varies greatly for different counter ions, while it changes slightly for common ions. However, Ra of bipolar membrane RXBM-1003 is affected by both counter ions and common ions. Ra declines significantly as solution concentration increases when the concentration is below 0.5 mol/L, and it has a relatively constant value when the concentration is above 1.0 mol/L.

Key words: ion-exchange membrane, area resistance, measuring method, influential facto

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