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›› 2013, Vol. 13 ›› Issue (2): 191-196.

• 反应与分离 • 上一篇    下一篇

沉降炉中生物质热解产物的脱硝特性

杨武 汪印 宋扬 姚常斌 刘跃进 许光文   

  1. 湘潭大学化工学院 中国科学院过程工程研究所多相复杂系统国家重点实验室 中国科学院过程工程研究所多相复杂系统国家重点实验室 中国科学院过程工程研究所,多相复杂系统国家重点实验室 湘潭大学化工学院 中国科学院过程工程研究所,多相复杂系统国家重点实验室
  • 收稿日期:2013-01-18 修回日期:2013-03-14 出版日期:2013-04-20 发布日期:2013-04-20
  • 通讯作者: 杨武

NO Reduction Characteristics of Biomass Pyrolysis Products in a Drop-tube Reactor

YANG Wu WANG Yin, SONG Yang YAO Chang-bin LIU Yue-jin XU Guang-wen   

  1. Institute of Chemical engineering National Key Laboratory of Multiphase Complex System, Institute of Process Engineering、Chinese Academy of Sciences State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, CAS State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences Institute of Chemical engineering, Xiangtan University (1. State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences
  • Received:2013-01-18 Revised:2013-03-14 Online:2013-04-20 Published:2013-04-20
  • Contact: YANG Wu

摘要: 利用连续沉降炉模拟白酒糟循环流化床解耦燃烧再燃区的反应气氛,研究各因素对半焦、焦油和热解气脱硝效率(比脱硝效率)的影响. 结果表明,反应温度由800℃升至1050℃,热解产物比脱硝效率均增大;半焦和焦油达到最佳比脱硝效率所需的停留时间为3.4 s;随反应气中NO浓度由400′10-6(j)增加到1000′10-6(j),热解产物比脱硝效率均呈降低趋势,但NO绝对还原量却呈增加趋势;随反应气中O2浓度增加,半焦比脱硝效率增大,热解气比脱硝效率降低,焦油比脱硝效率呈先增加后减少的趋势,在O2浓度为1.6%(j)时达最大,为60.1%. 在本研究的反应条件下,焦油比脱硝效率最好,热解气次之,半焦效果较差.

关键词: 热解, 生物质, 沉降炉, NO还原, 焦油

Abstract: A continuous drop-tube furnace was used to simulate the combustion conditions in the reburning zone of circulating fluidized bed decoupling combustion, and a series of experiments was conducted to study the NO reduction characteristics of pyrolysis products of distilled spirit lees, char, tar and pyrolysis gas, in terms of the specific NO reduction efficiency (hE) defined against the unit-mass flow reductant. The results indicated that with increasing of reaction temperature from 800 to 1050℃, hE of char, tar and pyrolysis gas increased. The optimal residence time for the possibly highest hE was 3.4 s for tar and char reductants. With increasing of NO concentration from 400′10-6(j) to 1000′10-6(j) in the reactant gas, the specific NO reduction efficiency decreased, but the reduced absolute NO amount increased for all the pyrolysis products. Increasing the O2 concentration in the reactant gas caused hE to decrease for char, to increase for pyrolysis gas and a parabola variation with increase first and then decrease for tar. At the O2 concentration of 1.63%(j), hE for tar was highest and reached 60.1%. This study demonstrated that unit-mass flow reactant tar enabled the highest NO reduction in comparison with char and pyrolysis gas.

Key words: pyrolysis, biomass, drop-tube furnace, NO reduction, tar

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