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›› 2014, Vol. 14 ›› Issue (6): 947-954.

• 过程与工艺 • 上一篇    下一篇

亚熔盐法粉煤灰脱铝渣水热处理后碱含量的影响因素

刘中凯 马淑花 郑诗礼 谢华 张懿 马海军   

  1. 中国矿业大学（北京）化学与环境工程学院 中国科学院过程工程研究所 中国科学院过程工程研究所 中国矿业大学化学与环境工程学院 中国科学院过程工程研究所 开曼铝业(三门峡)有限公司
  • 收稿日期:2014-10-29 修回日期:2014-12-01 出版日期:2014-12-20 发布日期:2014-12-20
  • 通讯作者: 刘中凯

Influential Factors of Alkaline Content in Alumina-removed Residue by Hydrothermal Treatment from Extraction Process of Alumina from Fly Ash with Sub-molten Salt Method

LIU Zhong-kai MA Shu-hua ZHENG Shi-li XIE Hua WANG Shao-na MA Hai-jun   

  1. School of Chemical & Environmental Engineering, China University of Mining & Technology Institute of Process Engineering, Chinese Academy of Sciences Institute of Process Engineering, Chinese Academy of Sciences (1. School of Chemical & Environmental Engineering, China University of Mining & Technology Institute of Process Engineering, Chinese Academy of Sciences The Cayman aluminum (Sanmenxia) Co., Ltd.
  • Received:2014-10-29 Revised:2014-12-01 Online:2014-12-20 Published:2014-12-20
  • Contact: LIU Zhong-kai

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摘要： 以亚熔盐法处理粉煤灰的脱铝渣为原料，采用动态水热法分解脱碱，研究了不同A/S(Al2O3/SiO2质量比)、C/S(CaO/SiO2质量比)和不同脱铝溶出工艺对硅渣碱含量的影响. 结果表明，随脱铝渣A/S增加，碱含量先降低后升高，脱铝渣A/S为0.11，硅渣Na2O含量降至1.18%，适当的A/S有利于提高硅渣中含铝托贝莫来石的晶化程度；脱铝渣C/S为0.98，硅渣Na2O含量仅有1.31%，随脱铝渣C/S增加，硅渣碱含量增加，C/S过高会降低硅酸钠钙(NaCaHSiO4)的分解率，不利于生成含铝托贝莫来石相；溶出时间和停留时间较长的脱铝渣在脱碱过程中不易生成含铝托贝莫来石.

关键词: 脱铝渣, 碱含量, 水热法, 溶出, 硅酸钠钙, 含铝托贝莫来石

Abstract: Aluminum-removed residue from in the exaction process of alumina from fly ash by sub-molten salt method was decomposed to recover sodium by dynamic hydrothermal method. The effects of mass ratio Al2O3 to SiO2 (A/S), mass ratio of CaO to SiO2 (C/S) and dissolution processes of aluminum-removed residue on the alkaline content in final silicate residue were examined. The results indicate that the sodium content decreases first and then increases with the increase of A/S, the sodium content in the silicate residue is as low as 1.28% when A/S is 0.11, appropriate A/S can help improve the crystallization degree of Al-substituted tobermorite in the silicate residue. The sodium content in the silicate residue is only 1.31% when C/S is 0.98, the sodium content decreases with the increase of C/S, and the decomposition rate of NaCaHSiO4 decreases at high C/S, which is not beneficial to formation of Al-substituted tobermorite. The aluminum-removed residue with longer dissolution time and residence time is not easy to generate Al-substituted tobermorite in the sodium removal process and causes the increase of sodium content in the final silicate residue.

Key words: aluminum-removed residue, alkaline content, hydrothermal method, dissolution, NaCaHSiO4, Al-substituted tobermorite

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