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›› 2001, Vol. 1 ›› Issue (1): 0-0.

• 1 •    

发泡剂ADC生成过程动力学分析

林诚,张济宇   

  1. 福州大学化学工程技术研究所,福建 福州 350002
  • 出版日期:2001-02-20 发布日期:2001-02-20

Physical Modeling of the Vortex Phenomenon in Continuous Casting Mould

LEI Hong, ZHU Miao-yong, HE Ji-cheng   

  1. LEI Hong, ZHU Miao-yong, HE Ji-cheng
  • Online:2001-02-20 Published:2001-02-20

摘要: 在玻璃搅拌反应器中进行了固体联二脲与氯气液相氧化反应生成发泡剂 ADC过程的传质与动力学实验, 提出了基于双膜理论的数学模型,以描述这一反应系统所涉及的气液和固液传质、固体溶解以及溶解物在液相中发生瞬间反应,特别是随反应进行固体反应物粒径变小导致固液传质速率减小的复杂过程. 模型能很好地描述实验结果. 依据模型估测的气液与固液传质系数值比较表明,气相反应物氯气的溶解传质过程是影响整个过程速率的主要控制步骤.

关键词: 发泡剂, 偶氮二甲酰胺, 传质, 气液固三相反应, 速率控制步骤

Abstract: Water model was used to study the mechanism of vortex formation in the mould, and the effects of operation parameters on vortex formation were investigated. The results show that singular vortex or a pair of vortices appear intermittently on the one side of nozzle, and the formation of vortex is due to the interaction of two surface streams flowing inwards. The frequency of vortex increases with the augment of the casting speed, and decreases with the augment of the immersion depth and nozzle angle. The formation of vortex can be inhibited by optimizing the submerged entry nozzle.

Key words: continuous casting, mould, vortex, physical modeling

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