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›› 2007, Vol. 7 ›› Issue (2): 332-336.

• 过程与工艺 • 上一篇    下一篇

利用CO-CO2-H2混合气体生产碳化铁的实验研究

王德永,闵义,刘承军,史培阳,姜茂发   

  1. 东北大学材料与冶金学院
  • 出版日期:2007-04-20 发布日期:2007-04-20

WANG De-yong,MIN Yi,LIU Cheng-jun,SHI Pei-yang,JIANG Mao-fa   

  1. College of Materials and Metallurgy, Northeastern University
  • Online:2007-04-20 Published:2007-04-20

摘要: 通过热力学计算,讨论了利用CO-CO2-H2混合气体生产碳化铁的可行性,并在实验室小型流化床反应器内使用CO-CO2-H2混合气体进行铁矿石还原实验,分别讨论了反应温度、系统压力、H2含量、CO/CO2比值等因素对碳化铁生成的影响. 扩大化的公斤级流化床实验表明,当反应时间为150 min时,铁矿石还原度超过95%,反应时间180 min时碳化铁率达到90%左右.

关键词: 废钢, 直接还原铁, 碳化铁, CO-CO2-H2混合气体, 尾气利用

Abstract: High grade scrap steel in the global market appears in the situation of demand exceeding supply with rapid development of short flow steelmaking, and iron carbide as a type of substitute for high grade scrape has some distinct advantages, its technology and production have become a focus in these years. In this work, the thermodynamic analysis was carried out to discuss the iron carbide production by using CO-CO2-H2 mixing gas, then, the reduction experiment of iron ore by using CO-CO2-H2 mixing gas was performed in a fluidized bed, and the key influential factors on iron carbide production, including temperature, system pressure, H2 content and CO/CO2 ratio, were investigated respectively. The experimental result of a kilogram-scale fluidized bed showed that the reduction grade exceeded 95% with 150 min reduction time, and after 180 min, iron carbide yield achieved about 90%.

Key words: scrap steel, direct reduction iron, iron carbide, CO-CO2-H2 mixing gas, waste gas utilization