欢迎访问过程工程学报, 今天是

›› 2013, Vol. 13 ›› Issue (5): 812-816.

• 反应与分离 • 上一篇    下一篇

不同絮凝剂对高泥氧化铜浸出液沉降的影响

郭艳华 戴惠新 杨俊龙   

  1. 昆明理工大学国土资源工程学院 昆明理工大学国土资源工程学院 昆明理工大学国土资源工程学院
  • 收稿日期:2013-05-22 修回日期:2013-07-03 出版日期:2013-10-20 发布日期:2013-10-20
  • 通讯作者: 郭艳华

Effects of Flocculants on Sedimentation of High-mud Copper Oxide Leaching Pulp

GUO Yan-hua Dai Hui-xin YANG Jun-long   

  • Received:2013-05-22 Revised:2013-07-03 Online:2013-10-20 Published:2013-10-20
  • Contact: GUO Yan-hua

摘要: 为解决云南某氧化铜现场生产中酸浸矿浆含泥量高、沉降速度慢、固液分离困难的问题,对其浸出矿浆进行絮凝沉降实验研究. 实验用浸出矿浆浓度为28.73%,考察了絮凝剂种类、用量、浓度对矿浆沉降的影响. 结果表明,明矾、十二烷基丙磺酸钠、聚丙烯酰胺、明胶、改性阴离子型聚丙烯酰胺、改性阳离子型聚丙烯酰胺均不能有效改善沉降速度,而改性非离子型聚丙烯酰胺(GH-6C)可使矿浆沉降速度大大加快. 这是由于GH-6C分子链上的官能团与浸出液中的胶体粒子发生吸附架桥作用,使颗粒逐渐变大而絮凝沉降. GH-6C分子量较大,在水相中流体力学尺寸或体积也较大,絮凝网捕能力也大,可有效降低絮凝剂的使用浓度、提高絮凝效率. GH-6C浓度为0.1%、用量为0.067 g/L时,沉降指标较好.

关键词: 高泥氧化铜, 浸出, 沉降, 絮凝剂, 改性非离子型聚丙烯酰胺

Abstract: In order to solve the problems of high mud content, slow sedimentation and solid-liquid separation difficulty of copper oxide leaching pulp, flocculation sedimentation experiments of the pulp were carried out with the pulp concentration at 28.73%, and the effects of type of flocculants, dosage of flocculants, and concentration of flocculants on the sedimentation examined respectively. The results show that alum, sodium dodecyl sulfonate, polyacrylamide, modified anionic polyacrylamide and modified cationic polyacrylamide cannot effectively improve the sedimentation speed. But the modified nonionic polyacrylamide can make the slurry sedimentation speed greatly accelerate, which is due to the adsorption bridging between the functional groups on the molecular chain of modified nonionic polyacrylamide and colloidal particles in the leaching liquid, leading to the particles size increasing gradually in flocculating sedimentation. Modified nonionic polyacrylamide has larger molecular weight, and fluid mechanics size or volume in water, so as to improving its ability for the flocculation, reducing the use of flocculant concentration effectively, and improving the flocculation efficiency. When the concentration of modified nonionic polyacrylamide is 0.1% and the dosage 0.067 g/L, the best sedimentation effect can be achieved.

Key words: high-mud copper oxide, leaching, sedimentation, flocculant, modified polyacrylamide

中图分类号: