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›› 2011, Vol. 11 ›› Issue (2): 254-258.

• 反应与分离 • 上一篇    下一篇

Extraction of Alumina from Coal Fly Ash with Sulfuric Acid Leaching Method

李来时 刘瑛瑛 翟玉春 吴玉胜   

  1. 沈阳市和平区和平北大街184号 沈阳铝镁设计研究院 沈阳市和平区和平北大街184号 沈阳铝镁设计研究院 沈阳工业大学材料科学与工程学院
  • 收稿日期:2011-01-19 修回日期:2011-03-16 出版日期:2011-04-20 发布日期:2011-04-20
  • 通讯作者: 李来时

Extraction of Alumina from Coal Fly Ash with Sulfuric Acid Leaching Method

LI Lai-shi LIU Ying-ying ZHAI Yu-chun WU Yu-sheng   

  1. Shenyang Aluminum and Magnesium Engineering and Research Institute Shenyang Aluminum and Magnesium Engineering and Research Institute School of Materials science and Engineering, Shenyang University of Technology
  • Received:2011-01-19 Revised:2011-03-16 Online:2011-04-20 Published:2011-04-20
  • Contact: LI Lai-shi

摘要: Coarse g-Al2O3 powder was prepared through acid leaching, solid-liquid separation, crystallizing and aluminum sulfate decomposing processes using coal fly ash and concentrated sulfuric acid as raw materials. The metallurgy level Al2O3 can be obtained by disposing coarse g-Al2O3 powder with Bayer process. The optimum conditions of acid leaching process were determined by experiments. The extraction rate of Al2O3 can be stabilized at about 87% under these conditions. The thermodynamics and kinetics of sulfuric acid leaching process were studied with irreversible thermodynamics.

关键词: coal fly ash, alumina, sulfuric acid, leaching, thermodynamics, kinetics

Abstract: Coarse g-Al2O3 powder was prepared through acid leaching, solid-liquid separation, crystallizing and aluminum sulfate decomposing processes using coal fly ash and concentrated sulfuric acid as raw materials. The metallurgy level Al2O3 can be obtained by disposing coarse g-Al2O3 powder with Bayer process. The optimum conditions of acid leaching process were determined by experiments. The extraction rate of Al2O3 can be stabilized at about 87% under these conditions. The thermodynamics and kinetics of sulfuric acid leaching process were studied with irreversible thermodynamics.

Key words: coal fly ash, alumina, sulfuric acid, leaching, thermodynamics, kinetics

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