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›› 2014, Vol. 14 ›› Issue (2): 234-240.

• 反应与分离 • 上一篇    下一篇

基于最佳氧化还原电位的O3-H2O2氧化法处理高浓度含锰废水

李天昕 刘祥萱 吴世玲 谷为民 UWIZEYIMANA Herman   

  1. 北京科技大学环境工程系 北京科技大学环境工程系 城市建设研究院 北京科技大学环境工程系
  • 收稿日期:2013-12-13 修回日期:2014-03-25 出版日期:2014-04-20 发布日期:2014-04-20
  • 通讯作者: 李天昕

Treatment of High Content Manganese-containing Wastewater by O3-H2O2 Oxidation Based on Optimal Redox Potential

LI Tian-xin LIU Xiang WU SAhi-ling GU Wei-min UWIZEYIMANA Herman   

  1. School of Civil and Environmental Engineering, University of Science and Technology Beijing School of Civil and Environmental Engineering, University of Science and Technology Beijing Academy of Urban Construction School of Civil and Environmental Engineering, University of Science and Technology Beijing
  • Received:2013-12-13 Revised:2014-03-25 Online:2014-04-20 Published:2014-04-20
  • Contact: LI Tian-xin

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摘要： 采用固定最佳氧化还原电位(ORP)的臭氧高级氧化与H2O2-NaOH深度氧化联用技术处理锰渣场渗滤水中高浓度Mn2+. 确定了氧化工艺的最佳OPR，并对臭氧、H2O2和NaOH投加量及氧化动力学进行研究. 结果表明，臭氧预氧化的最佳ORP为296~299.7 mV，两级臭氧投加量均为0.13~0.15 g/L，Mn2+氧化去除率达91.57%；H2O2-NaOH深度氧化最佳ORP为12.4~12.8 mV，在H2O2浓度2.0 g/L和NaOH浓度2.6 g/L且两者摩尔比为0.9:1(先加H2O2)的条件下，Mn2+去除率高达99.31%，出水Mn2+为1.2 mg/L，可达标排放. 臭氧和H2O2-NaOH对含锰废水的降解符合一级反应动力学，一、二级臭氧氧化的反应常数k固定ORP时分别为0.0762和0.0822 min-1，不固定ORP时分别为0.0279和0.0508 min-1，H2O2-NaOH氧化的反应常数固定ORP时为0.4758 min-1，不固定ORP时为0.3594 min-1.

关键词: 含锰废水, 臭氧预氧化, 最佳氧化还原电位, 高级氧化, 氧化反应动力学

Abstract: Ozonation and H2O2-NaOH advanced oxidation processes were used to treat high content manganese-containing wastewater based on optimal redox potential (ORP). The effects of oxidizer (ozone, H2O2 and NaOH) dosages, and the oxidation kinetics were investigated. Experimental results indicated that the ORP was 296~299.7 mV in the ozonation oxidation, under addition of ozone at 0.13~0.15 g/L in both first and second ozonation oxidation processes, the removal rate of Mn2+ reached 91.57%. The ORP was 12.40~12.80 mV in the H2O2-NaOH oxidation, when the dosages of H2O2 and NaOH were 2.0 and 2.6 g/L respectively, their molar ratio was 0.9:1 and H2O2 was added first, the removal rate of Mn2+ reached 99.31%. The treated wastewater had the Mn2+ concentration of 1.2 mg/L which was lower than the first level standard (2.0 mg/L) specified in the National Wastewater Discharge Standard GB 8978-1996. The oxidation kinetics indicated that the oxidation processes obeyed first order reaction kinetics. The rate constant k was 0.0762 min-1 for the first ozonation oxidation and 0.0822 min-1 for the second one at set ORP, otherwise k was 0.0279 and 0.0508 min-1, respectively. k was 0.4758 min-1 for the H2O2-NaOH oxidation at set ORP, otherwise k was 0.3594 min-1.

Key words: manganese-containing wastewater, ozonation oxidation, optimal redox potential, advanced oxidation, oxidation kinetics

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