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过程工程学报 ›› 2017, Vol. 17 ›› Issue (4): 751-756.DOI: 10.12034/j.issn.1009-606X.216347

• 反应与分离 • 上一篇    下一篇

国外某铜铅银钡多金属矿的分离与回收工艺

李春龙1,2, 苟延伟3, 先永骏1,2, 张汉平4, 吴 猛1,2, 付翔宇1,2, 柏少军1,2*   

  1. 1. 复杂有色金属资源清洁利用国家重点实验室,云南 昆明 650093: 2. 昆明理工大学国土资源工程学院,云南 昆明 650093; 
    3. 新疆宝地矿业股份有限公司,新疆 乌鲁木齐 838200;4. 昆明冶金高等专科学校,云南 昆明 650093
  • 收稿日期:2016-11-10 修回日期:2016-12-21 出版日期:2017-08-20 发布日期:2017-08-16
  • 通讯作者: 柏少军 baishaojun830829@126.com
  • 基金资助:
    微细粒级氧化锌矿物氯-氨耦合催化硫化机理研究

Separation and Recovery Process of Copper?Lead? Silver?Barium Polymetallic Ore from Abroad

Chunlong LI1,2,  Yanwei GOU3,  Yongjun XIAN1,2,  Hanping ZHANG4,  Meng WU1,2,  Xiangyu FU1,2,  Shaojun BAI1,2*   

  1. 1. State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming, Yunnan 650093, China;
     2. Faculty of Land Resources Engineering, Kunming University of Science & Technology, Kunming, Yunnan 650093, China;
     3. Xinjiang Treasure Land Mining Limited by Share Ltd., Xinjiang, Urumqi 838200, China; 
    4. Kunming Metallurgy College, Kunming, Yunnan 650093, China
  • Received:2016-11-10 Revised:2016-12-21 Online:2017-08-20 Published:2017-08-16

摘要: 对国外某铜铅银钡多金属矿进行铜铅混合浮选、抑铅浮铜、浸出、重选等实验研究,最终确定采用铜铅混浮?精矿浸出?尾矿重选的选冶联合工艺流程,实现了铜、铅、银、钡资源的综合回收. 结果表明,原矿含铜1.52%、铅7.84%和BaSO4 29.91%,银品位为243.8 g/t,经混合浮选得混合精矿含铜8.09%、铅47.21%、银1389.4 g/t,回收率分别为85.50%, 92.91%, 87.93%;在室温(25℃)、浸出剂浓度0.6 mol/L、液固质量比4、浸出时间50 min的条件下浸出,获得了铜、铅、银浸出率分别为84.95%, 5.56%, 21.04%的浸出液和含铜1.54%、铅64.23%、银1787.6 g/t的浸出渣. 浮选尾矿经摇床重选后得BaSO4品位为95.37%、回收率为35%的钡精矿.

关键词: 氧化铜, 混合浮选, 铜铅分离, 浸出, 重选

Abstract: For one copper?lead?silver?barium polymetallic ore from abroad, the mixed flotation of copper?lead and the tests of depress lead?coppe float, leach and gravity were conducted, ultimately, the dressing-metallurgy combination craft of copper lead mixed flotation?concentrate leaching?tailings gravity was employed, and the comprehensive utilization of copper, lead, silver and barium was realized. The results showed that raw ores contained 1.52% of copper, 7.84% of lead, 29.91% of barium sulfate, and 243.8 g/t of silver. A mixed concentrate containing 8.09% of copper with copper recovery rate of 85.50%, 47.21% of lead with lead recovery rate of 92.91%, 1389.4 g/t of silver with silver recovery rate of 87.93% was obtained after the processing of mixed flotation. Mixed copper and lead concentrate were leached under the following conditions: the leaching agent concentration 0.6 mol/L at room temperature (25℃), the liquid?solid mass ratio 4 and the extraction time 50 min. The leaching rates were copper 84.95%, lead 5.56%, and silver 21.04%. Moreover, a containing 1.54% of copper, 64.23% of lead and 1787.6 g/t of silver was produced. Finally, gravity separation of tabling was conducted for the leaching residue and a concentrate containing 95.37% of BaSO4 with a recovery rate of 35% was obtained.

Key words: copper oxide, mixed flotation, separation of copper and lead, leach, gravity separation