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›› 2012, Vol. 12 ›› Issue (2): 353-360.

• 综述 • 上一篇    

聚合物电解质膜燃料电池用电催化剂非碳载体的研究进展

姚传好 李钒 李翔 杨帆 徐梦迪 夏定国   

  1. 北京工业大学环境与能源工程学院 北京工业大学环境与能源工程学院 北京工业大学环境与能源工程学院 北京工业大学环境与能源工程学院 北京工业大学环境与能源工程学院 北京大学工学院
  • 收稿日期:2011-12-07 修回日期:2012-04-09 出版日期:2012-04-20 发布日期:2012-04-20
  • 通讯作者: 李钒

Research Progress in Non-carbon Materials Serving as Catalyst Support of Polymer Electrolyte Membrane Fuel Cells

YAO Chuan-hao LI Fan LI Xiang YANG Fan XU Meng-di XIA Ding-guo   

  1. College of Environmental and Energy Engineering, Beijing University of Technology College of Environmental and Energy Engineering, Beijing University of Technology College of Environmental and Energy Engineering, Beijing University of Technology College of Environmental and Energy Engineering, Beijing University of Technology College of Environmental and Energy Engineering, Beijing University of Technology College of Engineering, Peking University
  • Received:2011-12-07 Revised:2012-04-09 Online:2012-04-20 Published:2012-04-20
  • Contact: LI Fan

摘要: 综述了近年来非碳载体材料(碳化物、氧化物、复合型氧化物、亚化学计量钛氧化物等)的研究动态,介绍了其特点和制备方法,重点评价了以其为载体的铂基催化剂的催化活性及稳定性,并与目前普遍采用的商业碳载铂(Pt/C)催化剂进行了比较. 最后,对非碳材料用作载体存在的问题进行了分析,并对此类载体材料的发展方向进行了展望,提出高比表面、高电导率、高稳定性非碳载体材料的合成及载体与贵金属之间强相互作用机理的研究是载体研究的主要方向.

关键词: 非碳材料, 聚合物电解质膜燃料电池, 催化剂载体

Abstract: The recent research progress in non-carbon materials supports, such as carbide, oxide, composite oxide and sub-stoichiometric titanium oxide, is reviewed. Their characteristics and preparation methods are described briefly. The emphasis focuses on the catalytic activity and stability of Pt based catalysts supported on the materials. Comparison has been drawn between non-carbon supported and commercial carbon supported catalyst (Pt/C). Finally, the defects of non-carbon materials are summarized and outlook for the future development of this kind of support materials and further investigation of mechanism are provided in light of the current research status, regarding the preparation of materials with high specific surface area, high conductivity and superior stability, as well as mechanism of strong metal support interaction.

Key words: non-carbon material, polymer electrolyte membrane fuel cell, catalyst support

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