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›› 2012, Vol. 12 ›› Issue (3): 527-540.

• 综述 • 上一篇    

热载气体直接加热石油烃裂解研究进展?I. 裂解装置和技术

景晓东 赵月红 温浩 许志宏   

  1. 中国科学院过程工程研究所多相复杂系统国家重点实验室 中国科学院过程工程研究所 中国科学院过程工程研究所 中国科学院过程工程研究所
  • 收稿日期:2012-03-16 修回日期:2012-05-09 出版日期:2012-06-20 发布日期:2012-06-20
  • 通讯作者: 景晓东

Research Advances in Directly Heated Cracking of Hydrocarbonsby Heat Carrier Gas-I. Pyrolysis Apparatuses and Techniques

JING Xiao-dong ZHAO Yue-hong WEN Hao XU Zhi-hong   

  1. State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Science Institute of Process Engineering, CAS Institute of Process Engineering, CAS Institute of Process Engineering, CAS
  • Received:2012-03-16 Revised:2012-05-09 Online:2012-06-20 Published:2012-06-20
  • Contact: JING Xiao-dong

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摘要： 概述了以气体为热载体的石油烃直接加热裂解技术及其应用；介绍了热载气体直接加热石油烃裂解的装置组成、运行条件、产物产率、技术改进及发展状况，分析了裂解反应机理和反应动力学；指出热载气体直接加热裂解具有原料适用性广、产物分布灵活、热效率较高和受结焦影响小等优点，但同时也有裂解装置结构较复杂、缺乏系统性研究数据等不足. 最后对热载气体直接加热石油烃裂解的研究进行了展望，指出以氢氧燃烧产生的过热水蒸汽作为热载气体的直接加热裂解技术，在提高换热效率、降低碳排放、扩大原料范围和耦合制取合成气等方面有很大优势，发展前景广阔.

关键词: 热载气体, 直接加热裂解, 石油烃, 烯烃

Abstract: Recent advances in directly heated cracking using heat carrier gas together with the wide applications in industry are reviewed, focusing on the composition, operating conditions, product yields and the progress of pyrolysis apparatuses of directly heated cracking using heat carrier gas. In addition, the decoking techniques, mechanism and kinetics of hydrocarbons pyrolysis are also summarized up. Finally, the outlook for the future development of directly heated cracking using heat carrier gas is provided and a conclusion is drawn that directly heated cracking using superheated steam produced by combustion of hydrogen and oxygen as heat carrier gas will be one of the most promising techniques for it has the advantages of high feedstock and products flexibility, higher heat efficiency, and lower CO2 emission, and production of synthesis gas by coupling the decoking and pyrolysis processes.

Key words: heat carrier gas, directly heated cracking, hydrocarbons, olefins

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