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过程工程学报 ›› 2015, Vol. 15 ›› Issue (4): 670-676.DOI: 10.12034/j.issn.1009-606X.215200

• 材料工程专栏 • 上一篇    下一篇

稻壳制备活性炭联产二氧化硅工艺

孔艳 姚常斌 曾鸣 初茉 Vo Thi Diem Kieu 许光文   

  1. 中国矿业大学(北京)化学与环境工程学院 中国科学院过程工程研究所多相复杂系统国家重点实验室 中国矿业大学(北京)化学与环境工程学院 中国矿业大学(北京)化学与环境工程学院 胡志明科技大学 中国科学院过程工程研究所,多相复杂系统国家重点实验室
  • 收稿日期:2015-04-22 修回日期:2015-05-21 出版日期:2015-08-20 发布日期:2015-08-20
  • 通讯作者: 孔艳

Coproduction of Activated Carbon and Silica from Rice Husk

KONG Yan YAO Chang-bin ZENG Ming CHU Mo Vo Thi Diem Kieu XU Guang-wen   

  1. School of Chemical and Environmental Engineering,China University of Mining &Technology State Key Laboratory of Multi-phase Complex Systems,Institute of Process Engineering,Chinese Academy of Sciences School of Chemical and Environmental Engineering,China University of Mining &Technology School of Chemical and Environmental Engineering,China University of Mining &Technology Hochiminh city University of Technology (1. State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences
  • Received:2015-04-22 Revised:2015-05-21 Online:2015-08-20 Published:2015-08-20
  • Contact: KONG Yan

摘要: 采用物理法将稻壳炭化,炭化料用酸碱处理,固体残渣经高温水蒸汽活化制备活性炭,脱灰液体采用沉淀法制备SiO2. 结果表明,用2.5 mol/L NaOH溶液按液固比10 mL/g脱灰的炭化料所制活性炭比表面积为961.8 m2/g,比不脱灰炭化料所制活性炭增加136%,总孔容积增加103.8%,对碘和亚甲基蓝的吸附容量分别为1270和300 mg/g. 在10% HCl、煅烧温度600℃条件下所制SiO2粒径为40~60 nm,为无定型结构,比表面积达330 m2/g,纯度达99.84%.

关键词: 稻壳, 活性炭, 二氧化硅, 酸处理, 碱处理, 生物质残渣

Abstract: Coproduction process of activated carbon and silica with rice husk as raw material was studied. The carbonized rice husk was first treated by acid and alkali, the obtained solid residue was further activated to make activated carbon, and the sodium silicate solution was precipitated to prepare silica. The results showed that the specific surface area of activated carbon was 961.8 m2/g, and adsorption capacities of iodine and methylene blue were 1270 and 300 mg/g. Compared with such parameters of activated carbon from carbonized material without deashing, the specific surface area and total pore volume were increased by 136% and 103.8%, respectively. The optimal conditions for making silica were obtained as 10%(j) HCl and 2.5 mol/L NaOH in pretreatment and further calcination at 600℃. The particle size of obtained silica was about 40~60 nm with an amorphous structure. Its maximal specific surface area was 330 m2/g and purity 99.84%, respectively.

Key words: rice husk, activated carbon, silica, acid treatment, alkaline treatment, biomass residue

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