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›› 2009, Vol. 9 ›› Issue (3): 603-607.

• 材料工程专栏 • 上一篇    下一篇

UV固化环氧丙烯酸酯-纳米Al2O3颗粒复合涂层的性能

高鹏 薛向欣   

  1. 东北大学 材料与冶金学院 东北大学材料与冶金学院
  • 收稿日期:2008-12-02 修回日期:2009-03-09 出版日期:2009-06-20 发布日期:2009-06-20
  • 通讯作者: 薛向欣

Properties of UV Curable Epoxy Acrylate-Alumina Nanoparticles Composite Coating

GAO Peng XUE Xiang-xin   

  1. School of Materials and Metallurgy, Northeastern University School of Materials and Metallurgy, Northeastern University
  • Received:2008-12-02 Revised:2009-03-09 Online:2009-06-20 Published:2009-06-20
  • Contact: XUE Xiang-xin

摘要: 制备了UV固化环氧丙烯酸酯-纳米Al2O3复合涂料. 对纳米复合涂层的硬度、附着力、耐腐蚀性及热稳定性等性能进行了表征,并考察了纳米Al2O3对涂层性能的影响规律. 结果表明,涂层硬度及附着力先随纳米Al2O3添加量增加而提高,添加量为2%时,涂层附着力达1级;添加量为3%时,涂层铅笔硬度达6H;添加量继续增大,涂层硬度及附着力均下降. 对纳米复合涂层的热重分析和电化学阻抗谱分析结果表明,加入纳米Al2O3能提高涂层的热稳定性,但加入未改性纳米Al2O3使涂层的耐腐蚀性下降.

关键词: UV固化, 纳米复合材料, 环氧丙烯酸酯, 涂层

Abstract: UV curable epoxy acrylate-alumina nanocomposite coating was prepared. Its hardness, adhesion, corrosion resistance and thermal stability were characterized. The influences of nano-alumina on properties of coating were examined. The results show that the hardness and adhesion of coating were enhanced with increasing the amount of nano-alumina. When the amount was 2%, its adhesion would reach 1 grade. When the amount was 3%, pencil rigidity of coating would reach 6H. However, further increasing the amount of nano-alumina, its hardness and adhesion were decreased. TGA and EIS analysis results revealed that the addition of unmodified nano-alumina could improve thermal stability of the coating, but militated against corrosion resistance.

Key words: UV curable, nanocomposite, epoxy acrylate, coating

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