Pd/La0.5Pb0.5MnO3催化氧化甲苷合成葡萄糖醛酸

›› 2008, Vol. 8 ›› Issue (3): 572-575.

Pd/La0.5Pb0.5MnO3催化氧化甲苷合成葡萄糖醛酸

袁华孙炎彬邬茂杜治平闫志国吴元欣

武汉工程大学化工与制药学院绿色化工过程省部共建教育部重点实验室武汉工程大学化工与制药学院绿色化工过程省部共建教育部重点实验室武汉工程大学化工与制药学院绿色化工过程省部共建教育部重点实验室武汉工程大学化工与制药学院绿色化工过程省部共建教育部重点实验室武汉工程大学化工与制药学院绿色化工过程省部共建教育部重点实验室武汉化工学院化工与制药学院

收稿日期:2007-11-13 修回日期:2008-02-02 出版日期:2008-06-20 发布日期:2008-06-20
通讯作者: 袁华

Synthesis of Glucuronic Acid by Pd/La0.5Pb0.5MnO3 Catalytic Oxidation from Methyl Glucoside

YUAN Hua SUN Yan-bin WU Mao DU Zhi-ping YAN Zhi-guo WU Yuan-xin

School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology School of chemical engineering & pharmacy, Wuhan Institute of Chemical Technology

Received:2007-11-13 Revised:2008-02-02 Online:2008-06-20 Published:2008-06-20
Contact: YUAN Hua

摘要/Abstract

摘要： 采用沉淀法制备了以钙钛矿型复合金属氧化物为载体的催化剂Pd/La0.5Pb0.5MnO3，催化氧化甲基葡萄糖苷合成甲苷酸钠，进一步水解反应生成葡萄糖醛酸. 利用XRD和SEM对催化剂进行了表征，考察了催化剂制备和氧化工艺条件对葡萄糖醛酸收率的影响. 结果表明，在Pd负载量为1%、原料与催化剂质量比为6:1、温度70℃、压力为常压、pH值9、时间5 h的条件下，葡萄糖醛酸的收率达到29.5%，反应选择性较好.

关键词: 甲基葡萄糖苷, 葡萄糖醛酸, 催化氧化, Pd/La0.5Pb0.5MnO3负载型催化剂

Abstract: Glucuronic acid was synthesized by 1% Pd/La0.5Pb0.5MnO3 catalytic oxidation from methyl glucoside oxidized selectively. The support and catalyst samples were characterized by XRD and SEM techniques. The effects of different catalyst preparation methods and conditions of catalytic oxidation on the yield of glucuronic acid were studied. The results showed that the supports produced by sol-gel method and the catalyst prepared by precipitation had better catalytic activity, the yield of glucuronic acid reached 29.5% under the conditions of catalyst dosage 1/6 (based on glucoside mass), temperature 70℃, pH value 9, reaction time 5 h, and the ordinary pressure, and the catalyst had good selectivity.

Key words: methyl glucoside, glucuronic acid, catalytic oxidation, Pd/La0.5Pb0.5MnO3 catalyst

中图分类号:

O643

袁华孙炎彬邬茂杜治平闫志国吴元欣. Pd/La0.5Pb0.5MnO3催化氧化甲苷合成葡萄糖醛酸[J]. , 2008, 8(3): 572-575.

YUAN Hua SUN Yan-bin WU Mao DU Zhi-ping YAN Zhi-guo WU Yuan-xin. Synthesis of Glucuronic Acid by Pd/La0.5Pb0.5MnO3 Catalytic Oxidation from Methyl Glucoside[J]. , 2008, 8(3): 572-575.

[1]	刘再亮孟海玲周科刘庭蕾洪露. 微波-载铜活性炭催化氧化降解腐殖酸[J]. 过程工程学报, 2018, 18(4): 886-892.
[2]	郑昭韩云龙殷传慧李朋飞张浩. 铁矿石尾矿渣制备催化剂催化氧化甲醛[J]. 过程工程学报, 2015, 15(5): 871-875.
[3]	杨访宣绍峰马新胜. 纳米光催化网ACH/TiO2动态降解甲苯气体[J]. , 2015, 15(1): 164-168.
[4]	陈献袁杰费兆阳汤吉海崔咪芬乔旭. 流化床串联多段冷激式绝热固定床HCl氧化反应模拟优化[J]. , 2015, 15(1): 55-61.
[5]	黄建龙高保娇杨晓林. 交联聚苯乙烯微球负载N-羟基邻苯二甲酰亚胺催化剂对甲苯和环己醇氧化的催化性能[J]. , 2014, 14(4): 683-688.
[6]	季跃飞魏杰王东田. 4种DSA阳极的制备及其电催化性能比较[J]. , 2012, 12(2): 345-348.
[7]	杨成武曹烁左宜赞韩明汉. 氯化氢催化氧化制氯气催化剂的失活与再生[J]. , 2012, 12(2): 349-352.
[8]	成岳潘顺龙焦创王晶. Fe-MEL分子筛催化剂的制备及其催化脱色[J]. , 2012, 12(1): 148-153.
[9]	夏斌童志权黄妍罗晶罗河. CuSO4-CeO2/TS催化氧化NO及其抗H2O和SO2毒化性能[J]. , 2010, 10(1): 142-148.
[10]	李新柱杨树林任海伦. 铁取代介孔磷铝分子筛的合成、表征及其催化性能[J]. , 2009, 9(2): 408-412.
[11]	郑足红童华童志权张俊丰黄妍. 低温高活性NO氧化催化剂Mn-V-Ce/TiO2的制备与性能[J]. , 2008, 8(6): 1204-1212.
[12]	陈智涛韩明汉魏飞金涌. HCl催化氧化制氯气工艺过程[J]. , 2008, 8(5): 937-940.
[13]	吕树祥魏佳胡炀郭丽梅邓宇武文洁. Fe-ZSM-5分子筛催化剂催化降解高浓度含酚废水[J]. , 2008, 8(4): 751-755.
[14]	陈献;乔旭;王永;汤吉海;崔咪芬. 氯化氢氧化反应-脱水耦合制氯工艺[J]. , 2007, 7(5): 939-943.
[15]	雷智平;刘振宇;李秉正. 用于低温干法催化氧化所吸附苯酚的CuO-CeO2/AC吸附-催化剂[J]. , 2007, 7(4): 807-811.