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›› 2003, Vol. 3 ›› Issue (5): 0-0.

• 5 •    

KOH亚熔盐浸出低品位难分解钽铌矿的实验

周宏明,郑诗礼,张懿   

  1. 中国科学院过程工程研究所, 北京100080
  • 出版日期:2003-10-20 发布日期:2003-10-20

Leaching of a Low-grade Refractory Tantalum–Niobium Ore by KOH Sub-molten Salt

ZHOU Hong-ming, ZHENG Shi-li, ZHANG Yi   

  1. Biotechnology School, Southern Yangtze University, Key Laboratory of Industrial Biotechnology, Ministry of Education, Wuxi, Jiangsu 214036, China
  • Online:2003-10-20 Published:2003-10-20

摘要: 研究了低品位难分解钽铌矿的KOH亚熔盐浸出条件. 探讨了反应温度、初始KOH浓度、浸出时间和碱矿比等因素对铌和钽的浸出率的影响. 结果表明,铌和钽的浸出率分别可达98%和96%,较现行氢氟酸工艺提高10%以上,提高了难处理钽铌资源的利用率. 用无毒的KOH亚熔盐取代现行工艺中高浓高毒性的氢氟酸作为反应介质,从生产源头消除了F–的三废污染,为钽、铌湿法冶金开辟了一条新的途径.

关键词: KOH, 亚熔盐, 钽铌矿, 浸出

Abstract: Production of lignin peroxidase (LiP) and manganese peroxidase (MnP) in three kinds of reactors (stirred tank reactor, bubble column reactor and aeration reactor) by Phanerochaete chrysosporium was studied. High activity of enzymes, especially for LiP, was obtained in the aeration reactor. The production of enzymes and decoloration of orange I were investigated in semi-continuous culture and continuous culture respectively. High activity of enzymes for a long period of time was detected in the semi-continuous culture, in which five batches of dye wastewater could be decolored to more than 90% and the specific decloration rate of orange I was above 46.7 g/(g×d) when the proportion of replacement was 1/2, while enzymes decayed rapidly and poor decoloration was gained in the continuous culture. The application of semi-continuous culture in the aeration reactor was tried for the decoloration of four batches of printing-wastewater, and the decelerations rate of the first three was all above 90%.

Key words: KOH, sub-molten salt, niobium–tantalum ore, leaching

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