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›› 2012, Vol. 12 ›› Issue (3): 484-488.

• 生化工程专栏 • 上一篇    下一篇

滇池蓝藻在亚/超临界乙醇中热化学催化液化制备生物油及其特性

陈晓萍 包桂蓉 王华 李法社 李秀凤 杜威   

  1. 昆明理工大学 冶金节能减排教育部工程研究中心 昆明理工大学 冶金节能减排教育部工程研究中心 昆明理工大学冶金与能源工程学院 昆明理工大学冶金与能源工程学院 昆明理工大学冶金与能源工程学院 昆明理工大学冶金与能源工程学院
  • 收稿日期:2012-01-19 修回日期:2012-04-16 出版日期:2012-06-20 发布日期:2012-06-20
  • 通讯作者: 陈晓萍

Thermochemical Catalytic Liquefaction of the Cyanobacteria from Dianchi Lake in Sub- and Supercritical Ethanol, and Properties of Bio-oil

CHEN Xiao-ping BAO Gui-rong WANG Hua LI Fa-she LI Xiu-feng DU Wei   

  1. Engineering Research Center of Metallurgical Energy Conservation and Emission Reduction, Ministry of Education, Kunming University of Science and Technology Engineering Research Center of Metallurgical Energy Conservation and Emission Reduction, Ministry of Education, Kunming University of Science and Technology Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology
  • Received:2012-01-19 Revised:2012-04-16 Online:2012-06-20 Published:2012-06-20
  • Contact: CHEN Xiao-ping

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摘要： 在高压反应釜中，以亚/超临界乙醇为液化介质、以SO42-/ZrO2为催化剂催化液化滇池蓝藻制备生物油，考察了反应温度、反应时间、催化剂用量、料液比等对蓝藻液化效果的影响. 正交实验表明，反应温度270℃、反应时间40 min、催化剂SO42-/ZrO2加入量为蓝藻质量的2%、蓝藻与乙醇比为1:15 g/mL是最佳的条件，在此条件下液化率为87.46%，油产率为63.32%. 分析了生物油的特性和组分，生物油是一种组成复杂的有机混合物，其主要成分为十六烷酸乙酯.

关键词: 蓝藻, 亚/超临界乙醇, 催化液化, 生物油

Abstract: Direct liquefaction of the cyanobacteria from Dianchi Lake in ethanol under the sub- and supercritical conditions was carried out in an autoclave. The influences of reaction temperature, reaction time, catalyst loading, ratio of cyanobacteria to ethanol on the liquefaction were investigated. The results show that the optimal conditions are reaction temperature 270℃, reaction time 40 min, concentration of catalyst SO42-/ZrO2 2%, ratio of cyanobacteria to ethanol 1:15 g/mL. Under these conditions, the liquefaction conversion rate reaches 87.46% and the yield of bio-oil is 63.32%. The analysis by FT-IR and GC-MS indicates that the bio-oil is a complex mixture with palm ethyl as the main constituent.

Key words: cyanobacteria, sub- and supercritical ethanol, catalytic liquefaction, bio-oil

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