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›› 2009, Vol. 9 ›› Issue (5): 1017-1022.

• 材料工程专栏 • 上一篇    下一篇

工艺参数对铁尾矿制备泡沫玻璃性能的影响

张淑会 薛向欣 张淑卿   

  1. 河北理工大学冶金与能源学院 东北大学材料与冶金学院 河北理工大学研究生学院
  • 收稿日期:2009-04-03 修回日期:2009-06-30 出版日期:2009-10-20 发布日期:2009-10-20
  • 通讯作者: 张淑会

Influences of Process Parameters on Preparation of Foam Glass from Iron Ore Tailings

ZHANG Shu-hui, XUE Xiang-xin ZHANG Shu-qing   

  1. College of Metallurgy and Energy, Hebei Polytechnic University School of Materials and Metallurgy, Northeastern University College of Postgruate, Hebei Polytechnic University
  • Received:2009-04-03 Revised:2009-06-30 Online:2009-10-20 Published:2009-10-20
  • Contact: ZHANG Shu-hui,

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摘要： 以铁尾矿为主要原料、CaCO3和Na2CO3为发泡剂、Na3PO4×12H2O和硼砂(Na2B4O7×10H2O)为稳定剂，制备了性能良好的泡沫玻璃材料，并研究了工艺参数对制品性能的影响. 结果表明，CaCO3为主要发泡剂，Na2CO3含量对制品性能影响不大；Na3PO4×12H2O为主要稳定剂，Na2B4O7×10H2O含量不宜过多；发泡温度升高使制品孔径变大、容重和抗压强度降低；而烧结温度升高使制品的容重和抗压强度均先减小后增大. 制备泡沫玻璃适宜的工艺参数为(%, w)：基础玻璃84, CaCO3 3, Na2CO3 2, Na3PO4×12H2O 8, Na2B4O7×10H2O 3, 发泡温度900~950℃，烧结温度1100℃. 由此制得的泡沫玻璃材料容重约为2.05 g/cm3，抗压强度达62 MPa左右.

关键词: 铁尾矿, 泡沫玻璃, 工艺参数

Abstract: Foam glass with good capabilities was prepared from iron ore tailings with CaCO3 and Na2CO3 as blister, sodium phosphate and borax as stabilizer. The influences of different process parameters on sample capabilities were also studied. The results show that CaCO3 is the main blister, and Na2CO3 content has little effect on sample capabilities. Sodium phosphate is the main stabilizer, while the borax content should not be high. With the increase of foaming temperature the diameter size of sample increase, while bulk density and compression strength are reduced. The bulk density and compression strength all decrease firstly and increase subsequently when the sintering temperature increases. The optimal process parameters of preparation of foam glass are basic glass content 84%, CaCO3 3%, Na2CO3 2%, sodium phosphate 8%, borax 3%(w), foaming temperature 900~950℃, and sintering temperature 1100℃. Under above conditions, foam glass is made with bulk density 2.05 g/cm3 and compression strength around 62 MPa.

Key words: iron ore tailings, foam glass, process parameter