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过程工程学报 ›› 2016, Vol. 16 ›› Issue (4): 596-600.DOI: 10.12034/j.issn.1009-606X.215397

• 反应与分离 • 上一篇    下一篇

胺光气化法副产焦油中邻、间位甲苯二胺分离工艺优化及鉴别

白芳1,华超2,陆平3,梁向峰4,刘会洲2   

  1. 1. 中国科学院过程工程研究所绿色过程与工程重点实验室
    2. 中国科学院过程工程研究所分离工程与工程青年实验室
    3. 中国科学院过程工程研究所
    4. 中国科学院青岛生物能源与过程研究所
  • 收稿日期:2015-11-26 修回日期:2016-01-29 出版日期:2016-08-20 发布日期:2016-10-10
  • 通讯作者: 白芳 fbai@ipe.ac.cn

Separation and Recovery and Identification of Toluene Diamine from Byproduct Tar of Amine Light Gasification

BAI Fang 1,HUA Chao, 2,LU Ping 2,LIANG Xiang-feng 3,LIU Hui-zhou 4   

  1. 1. Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences
    2. Lab. Sep. Sci. & Eng., Inst. Process Eng., CAS
    3. Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences
    4.
  • Received:2015-11-26 Revised:2016-01-29 Online:2016-08-20 Published:2016-10-10
  • Contact: BAI Fang fbai@ipe.ac.cn

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摘要： 研究了胺光气化法副产焦油的分离工艺及邻、间位甲苯二胺(TDA)组成，采用降膜蒸发技术考察了压力、温度、转速、滴速对焦油中邻、间位甲苯二胺含量的影响，通过正交实验优化工艺条件，对焦油轻重组分中的TDA进行鉴别，优化分析条件. 结果表明，优化的分离条件为温度200℃、压力15 kPa、转速参数30 r/min、进料速率1.5 mL/min，该条件下甲苯二胺分离效果最佳，相对标准偏差为1.1%?1.5%.

关键词: 胺光气化法, 薄层色谱, 气相色谱, 邻位甲苯二胺, 间位甲苯二胺

Abstract: This work investigated the separation process and contents of ortho toluene diamine (O-TDA), metra toluene diamine (B-TDA) of by-product tar of amine light gasification. We discussed the effect of the pressure, temperature, speed, dripping speed on O-TDA, B-TDA contents in tar coupling with the falling film evaporation technology. The contents of TDA in the tar were quantitative identified by orthogonal experiment optimization. The results show that the optimal separation conditions are at temperature of 200℃, 15 kPa pressure, rotating speed of 30 r/min, and the feed rate of 1.5 r/min, then the separating efficiency is best with a relative standard deviation of 1.1%?1.5%.

Key words: amine light gasification, thin layer chromatography, gas chromatography, O-TDA, B-TDA

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