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›› 2008, Vol. 8 ›› Issue (3): 504-510.

• 过程与工艺 • Previous Articles     Next Articles

Extraction Separation of Fe3+ in Acid Dissolving Solution of Sub-molten Salt Reaction Product from Ilmenite with Tributyl Phosphate and Preparation of Rutile TiO2

MA Bao-zhong WANG Li-na QI Tao FENG Yang CHU Jing-long ZHANG Yi   

  1. Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences Institute of Process Engineering, Chinese Academy of Sciences Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences Beijing University of Chemical Technology Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences Institute of Process Engineering, Chinese Academy of Sciences
  • Received:2008-01-30 Revised:2008-02-28 Online:2008-06-20 Published:2008-06-20
  • Contact: QI Tao

磷酸三丁酯萃取分离钛铁矿亚熔盐反应产物酸解液中Fe3+及金红石型TiO2的制备

马保中 王丽娜 齐涛 冯杨 初景龙 张懿   

  1. 中国科学院过程工程研究所绿色过程与工程院重点实验室 中国科学院过程工程研究所绿色过程与工程重点实验室 中国科学院过程工程研究所绿色过程与工程重点实验室 北京化工大学 中国科学院过程工程研究所绿色过程与工程重点实验室 中国科学院过程工程研究所
  • 通讯作者: 齐涛

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Abstract: Extraction separation of ferric ions by solvent extraction method using tributyl phosphate (TBP) as extraction agent and sulfonic kerosene as thinner from the dissolved products of KOH and ilmenite in hydrochloric acid solution was studied. And TiO2 was prepared by hydrolyzing the raffinate. The effects of TBP concentration, hydrochloric acid concentration, concentration ratio of organic phase to aqueous phase (O/A) and extracting time on the extraction of ferric ions were investigated. The results showed that the extraction process was fast and the extraction rate of ferric ions increased with increasing the concentration of TBP and HCl concentration and decreasing the O/A ratio. The maximum extraction rate was larger than 99%. The reverse extraction rate using 1.0 mol/L NaCl solution reached 98%. The hydrolyzing product was rutile TiO2 spheres with the purity of more than 98%.

Key words: ilmenite, sub-molten salt method, tributyl phosphate, extraction, titanium dioxide

摘要： 在盐酸介质中以磷酸三丁酯(TBP)为萃取剂、磺化煤油为稀释剂，从钛铁矿与氢氧化钾亚熔盐反应产物的酸解液中萃取分离Fe3+，并利用萃取后的含钛液水解制备二氧化钛. 考察了萃取剂浓度、盐酸浓度、有机相和水相体积比(O/A)和萃取时间对铁萃取率的影响. 结果表明，钾系亚熔盐法分解钛铁矿的分解率在96%以上. 萃取率随着TBP浓度及盐酸浓度的增加和O/A值的减小而增大；通过调节萃取条件，萃取率可以达到99%以上. 用1.0 mol/L的NaCl溶液进行反萃，反萃率可达98%以上. 萃取后含钛液经水解可以制得纯度高于98%的金红石型TiO2球状颗粒.

关键词: 钛铁矿, 亚熔盐法, 磷酸三丁酯, 萃取, 二氧化钛

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