响应曲面优化粗锡真空蒸馏

doi:10.12034/j.issn.1009-606X.217301

过程工程学报 ›› 2018, Vol. 18 ›› Issue (3): 496-502.DOI: 10.12034/j.issn.1009-606X.217301

响应曲面优化粗锡真空蒸馏

蒲正浩^1,2,3，韩继标^1,2,3，李一夫^1,2*，杨斌^1,2,3，戴永年^1,2

1. 昆明理工大学真空冶金国家工程实验室，云南昆明 650093；2. 复杂有色金属资源清洁利用国家重点实验室，云南昆明 650093; 3. 云南省有色金属真空冶金重点实验室，云南昆明 650093

收稿日期:2017-08-14 修回日期:2017-10-20 出版日期:2018-06-22 发布日期:2018-06-06
通讯作者: 李一夫 29376154@qq.com
基金资助:
As-Pb混合蒸汽冷凝机理的研究

Optimization of Crude Tin Vacuum Distillation by Response Surface Methodology

Zhenghao PU^1,2,3, Jibiao HAN^1,2,3, Yifu LI^1,2*, Bin YANG^1,2,3, Yongnian DAI^1,2

1. National Engineering Lab for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming, Yunnan 650093, China; 2. State Key Laboratory of Complex Non-ferrous Metal Resources Clear Utilization, Kunming, Yunnan 650093, China; 3. Key Laboratory of Vacuum Metallurgy for Nonferrous Metal of Yunnan Province, Kunming, Yunnan 650093, China

Received:2017-08-14 Revised:2017-10-20 Online:2018-06-22 Published:2018-06-06
Contact: LI Yi-fu 29376154@qq.com

摘要/Abstract

摘要： 采用响应曲面法优化粗锡真空蒸馏工艺，研究了蒸馏温度、保温时间和原料质量对粗锡真空蒸馏提纯效果的影响. 结果表明，蒸馏温度和保温时间对粗锡真空蒸馏影响较大，原料质量的影响较小，蒸馏温度1350~1400℃、保温时间40~60 min时可有效去除粗锡中杂质. 以97.4185%的粗锡为原料，在蒸馏温度1400℃、保温60 min的条件下，锡纯度达99.8752%，含0.012% Pb, 0.045% Sb, 0.0005% Bi和0.0005% As，Fe和Cu含量无变化，Sn直收率达99.89%.

关键词: 粗锡, 真空蒸馏, 响应曲面法, 直收率

Abstract: Effects of the distillation temperature, the holding time and raw materials mass on vacuum distillation of crude tin were studied by response surface methodology. The results showed that the distillation temperature and holding time had remarkable influences and raw materials mass had little influence on vacuum distillation. The impurities in crude tin were effectively removed at 1350~1400℃ for 40~60 min. After vacuum distillation crude tin of 97.4185% at 1400℃ for 60 min, tin was purified up to 99.8752% with 0.012% Pb, 0.045% Sb, 0.0005% Bi, 0.0005% As with no variation of Fe and Cu content, and the direct recovery rate of tin was 99.89%.

Key words: crude tin, vacuum distillation, response surface methodology, direct recovery rate

蒲正浩韩继标李一夫杨斌戴永年. 响应曲面优化粗锡真空蒸馏[J]. 过程工程学报, 2018, 18(3): 496-502.

Zhenghao PU Jibiao HAN Yifu LI Bin YANG Yongnian DAI. Optimization of Crude Tin Vacuum Distillation by Response Surface Methodology[J]. Chin. J. Process Eng., 2018, 18(3): 496-502.

参考文献

[1] 宋兴诚.锡冶金[M].北京:冶金工业出版社, 2011:1.?
[2]Song X C.Tin metallurgy[M]. Metallurgical industry press, 2011:1.
[3]黄位森.锡 [M].北京:冶金工业出版社, 2001:1?
[4]Huang W S.Tin[M]. BeiJing: Metallurgical industry press, 2001:1.?
[5]王伟.来冶锡系统中砷的行为和分布的研究[J].大众科技, 2012, -(1):146-148
[6]Wang W.Study on the Behavior and Distribution of Arsenic in Tin Smelting Process in Laibin Smeltery[J]. Popular Science & Technology, 2012（1）:146-148[J].Popular Science & Technology, 2012, -(1):146-148
[7] 郭学益, 田庆华.高纯金属材料[M].北京:冶金工业出版社, 2010: 1-5.
[8]Guo X Y, Tian Q H.High-purity metal materials[M]. BeiJing: Metallurgical industry press, 2010: 1-5.
[9] 罗祥海.真空炉在锡精炼应用的探索[J].大众科技.2012, -(1):107-108[J].大众科技, 2012, -(1):107-108
[10]Luo X H.Application of Vacuum Furnace in Tin Refining process[J]. Popular Science & Technology, 2012, (1):107~108.[J].Popular Science & Technology, 2012, -(1):107-108
[11]森维，徐宝强，杨斌.真空碳热还原法制备碳化钛粉末[J].中国有色金属学报, 2011, 21(1):185-190
[12]Sen W, Xu B Q, Yang B.Preparation of TiC Powders by Carbothermal Reduction Method in Vacuum[J].Transactions of Nonferrous Metals Society of China, 2011, 21(1):185-190
[13]Yuan H B, Yang B, Xu B Q.Aluminum Production by Carbothermo-chlorination Reduction of Alumina in Vacuum[J].Transactions of Nonferrous Metals Society of China, 2010, 20(8):1505-1510
[14]李亮，刘大春，杨斌，等.真空蒸馏铅阳极泥制备粗锑的研究[J].真空科学与技术学报, 2012, 32(4):301-305
[15]Li L, Liu D C, Yang B, et al.Extracting of Crude Antimony from Lead Anode Slime by Vacuum Distillation[J].Journal of Vacuum Science and Technology, 2012, 32(4):301-305
[16]李一夫, 王安祥, 杨斌等.粗锡真空蒸馏精炼的研究真空科学与技术学报[J].真空科学与技术学报, 2015, 35(3):334-337
[17]Li Y F, Wang A X, Yang B, et al.Refinement of Crude Tin by Vacuum Distillation on Industrial ScaleChinese Journal of Vacuum Science and Technology,2015,(3): 334-337[J].Chinese Journal of Vacuum Science and Technology, 2015, 35(3):334-337
[18]丘克强, 李晓勇, 戴永年.高砷焊锡真空蒸馏脱铅砷[J].中国有色金属学报, 1993, 3(4):30-33
[19]Qiu K Q, Li X Y, Dai Y N.Removal of Arsenic from High-Arsenic solder by Vacuum Distillation[J].Chinese Journal of nonferrous metals, 1993, 3(4):30-33
[20]杨斌、戴永年, 等.真空蒸馏分离锡锑合金的研究[J].昆明理工大学学报, 1998, 23(3):104-107
[21]Yang B, Dai Y N, et al.Study on separation of Tin-antimony alloy by vacuum distillation[J].Journal of Kunming University of Science and Technology, 1998, 23(3):104-107
[22] 张于轩.多响应问题的稳健性设计优化研究[D]. 天津.天津大学.硕士论文, 2004: 21-23.
[23]Zhang Y X.A Study on Robust Design Optimization for Multiple Response Problems[D].TianJin. Master Thesis of Tianjin University, 2004: 21-23.
[24]Bourquin J.Schmidli H,Hoogevest P. Leuenberger H. Comparison of artificial neural networks (ANN) with classical modelling techniques using different experimental designs and data from a galenical study on a solid dosage form[J].European Journal of Pharmaceutical Sciences, 1998(7): 287-300.[J].European Journal of Pharmaceutical Sciences, 1998, 6(4):287-300
[25]Kandimalla K.K.,Kanikkannan N,Singh MOptimization of a vehicle mixture for the transdermal delivery of melatonin using artificial neural networks and response surface method[J].Journal of Controlled Release, 1999, 61(1-2):71-82
[26] 杨静.玉米秸秆纤维素酶水解研究及响应曲面法优化[D].天津.天津大学硕士论文, 2007: 24-25.
[27]Yang J.Study on cellulase hydrolysis of corn stalk and optimization by Response Surface Methodology[D].TianJin. Master Thesis of Tianjin University, 2007: 24-25.
[28]Kima M.S.,Kima JS，You YH.Park HJ.,Lee S.,Park JS. Development and optimization of a novel oral controlled delivery system for tamsulosin hydrochloride using response surface methodology[J].International Journal of Pharmaceutics, 2007, 341(1-2):97-104
[29]张佼, 孙宝德, 饶群力, 陈刚, 葛爱景.高纯铝定向凝固中晶粒的生特性[J].上海交通大学学报, 2005, 39(11):1787-1791
[30]Zhang J, Sun B D, Rao Q L, Chen G, Ge A J.The Growth of High Purity Aluminum Grains during Directional Solidification[J].JOURNAL OF SHANGHAI JIAOTONG UNIVERSITY, 2005, 39(11):1787-1791
[31] Kubaschewski O, Aicock C B.冶金热化学[M].北京:冶金工业出版社, 1985:486- 505.
[32]Kubaschewski O, Aicock C B.Metallurgical thermochemistry[M]. BeiJing: Metallurgical industry press, 1985:486- 505.
[33] Lai Y B, Guo Z C, Huang H, Wang S, Zhang H Y.Lai Y, Guo Z, Huang H, et al. Synthesis of high tap density spherical micro-size silver particles by liquid-phase reduction using response surface methodology[J]. Journal of Materials Science Materials in Electronics, 2014, 25(4):1893-1900.[J].Journal of Materials Science Materials in Electronics, 2014, 25(4):1893-1900
[34] Rasoul K N, Fereshteh R.Using design of experiments in synthesis of ultra-fine copper particles by electrolysis[J]. Powder Technology, 2013, 237:165-171.[J].Powder Technology, 2013, 237(3):165-171
[35] Oktay C, Nevzat A, ?brahim A, G?khan T.Optimization of some parameters of stirred mill for ultra-fine grinding of refractory Au/Ag ores [J]. Powder Technology, 2011, 208:121-127.[J].Powder Technology, 2011, 208(1):121-127
[36] Ghadiri M, Vatanara A, Doroud D.Paromomycin loaded solid liquid nanoparticles: characterization of production parameters [J]. Biotechnology and Bioprocess Engineering, 2011, 16: 617-623.[J].Biotechnology and Bioprocess Engineering, 2011, 16(6):617-623

响应曲面优化粗锡真空蒸馏

Optimization of Crude Tin Vacuum Distillation by Response Surface Methodology

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