氧化铝载体改性及其应用研究进展

doi:10.12034/j.issn.1009-606X.218280

摘要/Abstract

摘要： 氧化铝不仅价格低廉、易获取，且具有多孔性、大比表面积、高分散性、高热稳定性等优点，常用作催化剂载体，广泛应用于工业催化领域。氧化铝的孔结构对工业催化剂性能影响很大。为优化氧化铝载体的性能，对氧化铝的扩孔和添加助剂改性已进行了大量研究。扩孔改性可降低扩散阻力并改善传质、提高活性位点的有效利用率、增强抗结焦性能，进而提高加氢催化的产率；添加助剂改性可有效抑制氧化铝载体高温烧结和相变，防止孔结构被破坏，提高催化剂的寿命。本工作介绍了制备氧化铝的方法?拟薄水铝石脱水法和溶胶?凝胶法，综述了氧化铝的扩孔方法，总结了改性氧化铝载体的最新研究进展，包括自组装法、水热处理法、扩孔剂法；阐述了氧化铝添加助剂的改性方法，包括加入稀土金属氧化物、碱(土)金属氧化物、其它金属氧化物及非金属氧化物。最后，展望了氧化铝未来的研究和发展方向。

关键词: 载体, 氧化铝, 制备, 活性

Abstract: Alumina, which is not only inexpensive and easy to obtain, but also has many advantages such as porosity, large specific surface area, high dispersibility and high thermal stability. Therefore, alumina is often used as catalyst carrier and widely used in the catalysis of petroleum industry. The pore structure of alumina has a great influence on the catalytic reaction of the catalyst, especially in mass transfer. In order to optimize the performance of alumina carrier, a lot of studies have been carried out on the pore expansion of alumina and the modification of alumina by adding additives. Pore enlargement can not only reduce the material diffusion resistance and improve mass transfer, but also improve the effective utilization of active sites and enhance the anti-coking performance. Thus, the yield of hydrogenation catalysis can be increased. The high temperature sintering and phase transformation of alumina support can be effectively inhibited by the addition of catalyst support modified by additives. In this way, the pore structure can be prevented from being destroyed and the service life of the catalyst can be prolonged. In this work, the methods for preparing alumina were pseudo boehmite dehydration and sol?gel method. Pore expanding methods of alumina, including self-assembly method, hydrothermal treatment method and pore expanding agent method, were reviewed. The modification methods of alumina additives were described, including rare earth metal oxides, alkali (earth) metal oxides, other metal oxides and non-metal oxides. The latest research progress of modified alumina carriers was summarized. Finally an outlook for the future research and development of alumina as catalyst support was given. The existing modification methods of alumina still cannot meet the market demand. The preparation of alumina carriers for specific reactions is still the main research content at present. Four key aspects of future research on alumina carriers were proposed.

Key words: support, alumina, preparation, reactivity

孙克宁马茜茜侯瑞君李敏香张春刚. 氧化铝载体改性及其应用研究进展[J]. 过程工程学报, 2019, 19(3): 465-472.

Kening SUN Xixi MA Ruijun HOU Minxiang LI Chungang ZHANG . Research progress in modification of alumina support and its application[J]. Chin. J. Process Eng., 2019, 19(3): 465-472.

参考文献

[1]SAAD F, COMPAROT J D, BRAHMI R, et al..Influence of acid-base properties of the support on the catalytic performances of Pt-based catalysts in a gas-phase hydrogenation of acetonitrile[J].Applied Catalysis A: General, 2017, 544(544):1-9 [2] DIMAS-RIVERA G L, DE LA ROSA J R, LUCIO-ORTIZ C J, et al.Bimetallic Pd-Fe supported on gamma-Al2O3 catalyst used in the ring opening of 2-methylfuran to selective formation of alcohols[J].Applied Catalysis A: General, 2017, 543(543):133-140 [3] XIE T, WANG J, DING F, et al.CO2 hydrogenation to hydrocarbons over alumina-supported iron catalyst: Effect of support pore size [J].Journal of CO2 Utilization, 2017, 19(19):202-207 [4] ZHANG C, YANG H, GAO P, et al.Preparation and CO2 hydrogenation catalytic properties of alumina microsphere supported Cu-based catalyst by deposition-precipitation method[J].Journal of CO2 Utilization, 2017, 17(17):263-272 [5]桑小义, 李会峰, 李明丰, 等.含氧化合物加氢脱氧的研究进展[J].石油化工, 2014, 43(4):466-473 [6]WANG H, CAO Y, LI, D, et al.Catalytic hydrorefining of tar to liquid fuel over multi-metals (W-Mo-Ni) catalysts[J].Journal of Renewable and Sustainable Energy, 2013, 5(5):1-14 [7]GALINDO I R, DE LOS REYES J A.Effect of alumina-titania supports on the activity of Pd,Pt and bimetallic Pd-Pt catalysts for hydrorefining applications[J].Fuel Processing Technology, 2007, 88(9):859-863 [8]PURóN H, PINILLA J L, MONTOYA DE LA FUENTE J A, et al.Effect of Metal Loading in NiMoA12O3 Catalysts on Maya Vacuum Residue Hydrocracking[J].Energy＆Fuels, 2017, 31(5):4843-4850 [9]KIAMBI S L.Catalytic Hydrocracking of Waste Vegetable Oil Using High Pressure Flow Apparatus to Obtain Jet Fuel Range Alkanes[J].Journal of the Chemical Society of Pakistan, 2016, 38(3):588-593 [10]曹东学, 冯敢, 任坚强, 等.铂铼重整催化剂的最佳氯含量[J].石油炼制与化工, 2000, 31(9):33-36 [11] YANG P, LI J, CHENG Z, et al.Promoting effects of Ce and Pt addition on the destructive performances of V2O5/gamma-Al2O3 for catalytic combustion of benzene[J].Applied Catalysis A: General, 2017, 542(542):38-46 [12]孙杰, 孙春文, 李吉刚, 等.甲烷水蒸气重整反应研究进展[J].中国工程科学, 2013, 15(2):98-106 [13]姜洪涛, 华炜, 计建炳.甲烷重整制合成气镍催化剂积炭研究[J].化学进展, 2013, 25(5):859-868 [14]陈建设, 王淑娟, 李金兵, 等.环氧乙烷银催化剂的研究进展[J].石油化工, 2015, 44(7):893-899 [15] TSENG H H, WANG C T, ZHYANG G L, et al.Enhanced H2/CH4 and H2/CO2 separation by carbon molecular sieve membrane coated on titania modified alumina support: Effects of TiO2 intermediate layer preparation variables on interfacial adhesion2016, 510: 391-404.[J].Journal of Membrane Science, 2016, 510(510):391-404 [16]孙雪芹, 潘志爽, 张爱萍, 等.改性对γ-酸性和催化活性的影响[J].炼油与化工, 2017, 28(3):7-9 [17]张超, 聂红, 高晓冬, 等.载体表面性质对活性相形貌结构及植物油加氢脱氧选择性的影响[J].石油学报石油加工, 2015, 31(4):845-852 [18]杨勇, 桓源峰, 曹敏.镧、锆改性的氧化铝载体对钯催化氧化甲烷活性的影响[J].化学研究, 2015, 26(3):292-297 [19] ZHANG Y, ZHOU Y, PENG C, et al.Enhanced activity and stability of copper oxide/gamma-alumina catalyst in catalytic wet-air oxidation: Critical roles of cerium incorporation[J].Applied Surface Science, 2018, 436(436):981-988 [20] PARK J H, YEO S, KANG T J, et al.Enhanced stability of Co catalysts supported on phosphorus-modified Al2O3 for dry reforming of CH4[J].Fuel, 2018, 212(212):77-87 [21]PANCHENKO V N, DANILOVA I G, ZAKHAROV V A, et al.Effect of the acid-base properties of the support on the catalytic activity of ethylene polymerization using supported catalysts composed of Cp2ZrX2 (X = Cl,Me) and Al2O3(F)[J].Reaction Kinetics Mechanisms and Catalysis, 2017, 122(1):275-287 [22]于海斌, 崔晓萌, 孙彦民.等. 前驱体合成方法对γ-氧化铝性质的影响研究[J].无机盐工业, 2017, 49(1):52-55 [23] 任先廷, 李威, 郭智峰.碳化法生产拟薄水铝石工业实践 2005(5):39-40.[J].有色金属(冶炼部分), 2005, 5(5):39-40 [24] 孙成才, 任先廷.拟薄水铝石生产的优化设计2005(8): 18-20.[J].轻金属, 2005, 8(8):18-20 [25]黄世勇, 王秋萍, 黄媚, 等.碳化法制备拟薄水铝石过程中助剂作用的研究[J].化工技术与开发, 2017, 46(10):5-8 [26]王楚, 冯辉霞, 梁顺琴, 等.法大孔拟薄水铝石的制备及其应用[J].工业催化, 2015, 23(7):541-544 [27]王楚, 冯辉霞, 梁顺琴, 等.成胶条件对硫酸铝-氨水法制备拟薄水铝石物性的影响[J].石化技术与应用, 2015, 33(2):125-128 [28] 饶拴民, 朱建军, 杜海荣.大孔容活性氧化铝的用途和制备方法[J].轻金属, 2002, 3(3):17-19 [29]赵鹏泽, 刘冬梅, 王海彦, 等.大孔介孔氧化铝的制备及加氢性能研究[J].应用化工, 2017, 46(2):335-338 [30] 杜安睿, 姜涛, 李骞, 等.废铝基/钯催化剂碱性浸出废液制备拟薄水铝石的研究.[J].矿产保护与利用, 2018, 1(1):112-122 [31]曾丰, 杨清河, 曾双亲.采用-连续中和法制备拟薄水铝石[J].石油学报石油加工, 2015, 31(5):1069-1074 [32]唐国旗, 张春富, 孙长山, 等.碳化法制备拟薄水铝石技术的研究进展[J].工业催化, 2011, 19(4):21-25 [33]左少卿, 杜晓辉, 熊晓云, 等.拟薄水铝石制备方法的研究进展[J].应用化工, 2017, 46(9):1818-1821 [34] 王秋萍, 黄青则, 黄媚, 等.双铝法合成拟薄水铝石的优化研究[J]. , 2017, 7: 1-4.[J].化工技术与开发, 2017, 46(7):1-4 [35] 佟佳, 吕振辉, 张学辉.大孔容孔径氧化铝的合成研究[J]. , 2016, 6: 1104-1107.[J].当代化工, 2016, 45(6):1104-1107 [36] 刘文洁, 隋宝宽, 袁胜华, 等.硫酸铝法制备拟薄水铝石过程研究[J]. , 2016, 1: 27-31.[J].石油炼制与化工, 2016, 47(1):27-31 [37]张哲民, 杨清河, 聂红, 等.法制备拟薄水铝石成胶机理的研究[J].石油化工, 2003, 32(7):552-554 [38]李凯荣, 谭克勤, 石芳, 等.一种低标贯密度大孔球形氧化铝的制备[J].无机盐工业, 2003, 35(1):16-18 [39]游咏, 匡加才.溶胶-凝胶法在材料制备中的研究进展[J].高科技纤维与应用, 2002, 27(2):12-15 [40] 姚楠, 熊国兴, 盛世善, 等.溶胶凝胶法制备中孔分布集中的氧化铝催化材料[C]. 燃料化学学报, 2001: 80-82. [41]刘超, 成国祥.模板法制备介孔材料的研究进展[J].离子交换与吸附, 2003, 19(4):374-384 [42]AGUADO J, CASTRO M C, PAREDES B, et al.Sol-gel synthesis of mesostructured γ-alumina templated by cationic surfactants[J].Microporous and Mesoporous Materials, 2005, 83(1-3):181-192 [43] 林小羽.油脂催化裂解与非均相催化酯化制备生物燃油基础研究(摘要)[J].生物质化学过程, 2013, 47(4):57-57 [44]李睿, 袁桂梅, 陈胜利, 等.有序介孔氧化铝的制备及其在丁烯歧化中的应用[J].燃料化学学报, 2012, 40(7):855-860 [45]李红, 陈胜利, 董鹏, 等.新型大孔结构重油加氢催化剂的制备、表征与评价[J].燃料化学学报, 2009, 37(4):444-447 [46]谢小化, 孟秀红, 施岩, 等.以聚苯乙烯为模板剂制备有序大孔氧化铝[J].当代化工, 2014, 43(11):2234-2237 [47]王鼎聪.纳米自组装合成大孔容介孔氧化铝[J].中国科学辑:化学, 2009, 39(5):420-431 [48]WANG D.Large pore volume mesoporous aluminumoxide synthesized via nano-assembly[J].Science in China Series B: Chemistry, 2009, 52(12):21114-21114 [49]王爽, 丁巍, 王鼎聪, 等.二次纳米自组装大孔氧化铝贯穿孔道的形成机理[J].无机化学学报, 2015, 31(8):1539-1547 [50]丁巍, 王鼎聪, 赵德智, 等.纳米自组装催化剂金属分散度对催化活性的影响[J].现代化工, 2014, 34(5):113-116 [51]王鼎聪, 刘纪端.贯穿式框架式渣油脱金属催化剂氧化铝载体的研究[J].石油炼制与化工, 2010, 41(1):31-35 [52] WANG D.A novel idea on high interior phase emulsion[J]., 2003, 286: 91- 95.[J].Science, 2003, 286(286):91-95 [53]WANG D.A study of identifying the emulsion type of surfactant: Volume balance value[J].Journal of colloid and interface science, 2002, 247(2):389-389 [54]闫玉玲, 宋锦玉, 王鼎聪.超增溶法纳米-催化剂的表征及自组装机理分析[J].石油化工高等学校学报, 2014, 27(4):21-26 [55]刘岩, 商丽艳, 李艳, 等.纳米氧化铝载体的制备及孔性质研究[J].石油化工高等学校学报, 2010, 23(2):13-15 [56]李艳, 王鼎聪, 赵杉林, 等.超增溶自组装制备纳米氧化铝渣油加氢催化剂载体[J].工业催化, 2008, 16(12):39-42 [57]STANISLAUS A, AL-DOLAMA K, ABSI-HALABI M.Preparation of a large pore alumina-based HDM catalyst by hydrothermal treatment and studies on pore enlargement mechanism[J].Journal of Molecular Catalysts A: Chemical, 2002, 181(1-2):33-39 [58]李国印, 俞杰.高温水蒸气处理对氧化铝孔结构的影响[J].石油炼制与化工, 2014, 45(4):31-35 [59]黄伟莉, 刘百军, 孙发民, 等.拟薄水铝石脱水产物γ-在较低温度下的再水合过程研究[J].工业催化, 2004, 12(10):44-48 [60] 孔维萍, 王聪, 徐丹丹, 等.高温水热法合成系列介孔氧化铝负载铂催化剂及其对苯的催化燃烧性能[J].吉林大学学报（理学版）, 2014, 3(3):601-604 [61] LI H, LI M, NIE H.Tailoring the surface characteristic of alumina for preparation of highly active NiMo/Al2O3 hydrodesulfurization catalyst[J].Microporous and Mesoporous Materials, 2014, 188: 30-36., 188(4):30-36 [62]胡大为, 杨清河, 聂红, 等.活性氧化铝载体的扩孔及改性[J].石油炼制与化工, 2004, 35(8):46-49 [63]李广慈, 赵会吉, 赵瑞玉, 等.不同扩孔方法对催化剂载体氧化铝孔结构的影响[J].石油炼制与化工, 2010, 41(1):49-53 [64]LIU, J, LI Y, LI Y, et al.Effects of pore structure on thermal conductivity and strength of alumina porous ceramics using carbon black as pore-forming agent[J].Ceramics International, 2016, 42(7):8221-8228 [65] 田志坚, 蒲延芳, 徐云鹏, 等.改性氧化铝载体和由该载体制成的加氢催化剂及制备方法: 中国, 101590433A[P]. 2009-12-02. [66]MITRAN G, MAKó é, RéDEY á, et al.Esterification of acetic acid with n-Butanol using vanadium oxides supported on γ-alumina[J].Comptes Rendus Chime, 2012, 15(9):793-798 [67]李赫, 姚文君, 黄德华, 等.全馏分裂解汽油选择性加氢钯催化剂[J].石化技术与应用, 2010, 28(3):215-217 [68]张永刚, 闫裴.活性氧化铝载体的孔结构[J].工业催化, 2000, 8(6):14-18 [69]LI G, LU X, TANG Z, et al.Preparation of NiMogamma-Al2O3 catalysts with large pore size for vacuum residue hydrotreatment[J].Materials Research Bulletin, 2013, 48(11):4526-4530 [70]KONG X, CHEN L.Chemoselective hydrogenation of aromatic aldehydes over SiO2 modified Coγ-Al2O3[J].Applied Catalysis A: General, 2014, 476(22):34-38 [71]赵檀, 赵野, 孙发民, 等.硅改性--复合载体负载催化剂的加氢性能[J].石油化工, 2014, 43(10):1156-1160 [72]ALSHAIBANI A, YAAKOB Z, ALSOBAAI A, et al.Effect of chemically reduced palladium supported catalyst on sunflower oil hydrogenation conversion and selectivity[J].Arabian Journal of Chemistry, 2017, 10(1):S1188-S1192 [73]陈雪莹, 乔明华, 贺鹤勇.载体对负载型-催化剂催化-乙基蒽醌加氢制反应性能的影响[J].催化学报, 2011, 32(2):325-332 [74] JABBARNEZHAD P, HAGHIGHI M, TAGHAVINEZHAD P.Sonochemical synthesis of NiMo/Al2O3-ZrO2 nanocatalysts: Effect of sonication and zirconia loading on catalytic properties and performance in hydrodesulfurization reaction[J].Fuel Processing Technology, 2014, 126: 392-401., 126(10):392-401 [75]何婷婷, 付庆涛, 刘晨光.改性--催化剂的苯选择性加氢性能[J].化学反应工程与工艺, 2014, 30(2):128-132 [76]LIU C, ZHOU Z, HUANG Y, et al.Support effects on thiophene hydrodesulfurization over Co-Mo-NiAl2O3 and Co-Mo-NiTiO2-Al2O3 catalysts[J].Chinese Journal of Chemical Engineering, 2014, 22(4):383-391 [77]鄢景森, 王海彦, 李素魁, 等.载体对催化剂加氢脱氮反应性能的影响[J].燃料化学学报, 2014, 42(3):362-369 [78] 中国石油大学(北京).以磷改性氧化铝为基质原位合成SAPO 11@γ Al2O3复合载体材料的方法: 中国, 201611152085.0[P]. 2016-12-14. [79] 李红跃, 王雷, 潘一, 等.改性氧化铝吸附剂脱除焦化蜡油中氮化物的研究[J].石化技术与应用, 2016, 34(4):270-273 [80] 唐莉, 孙雪芹, 刘丛华, 等.磷改性对γ-Al2O3酸性和催化活性的影响[J]. , 2012, 10: 1785-1787.[J].应用化工, 2012, 28(3):1785-1787 [81] 李强, 马智.活性氧化铝在FCC催化剂中的应用研究[J].工业催化, 2006, 14(1):65-67 [82] 曾鹤, 施岩, 李鹤鸣, 等.氧化铝和磷改性对非负载型催化剂结构和加氢脱硫性能的影响[J]. , 2016, 8: 951-959.[J].应用化学, 2016, 33(8):951-959 [83] 张孔远, 韩红亮, 周然然, 等.磷改性拟薄水铝石性能及在蜡油加氢催化剂中的应用[J].工业催化, 2010, 18(2):37-41 [84] 温德荣, 喻正南, 梁相程, 等.FF-26加氢裂化预处理催化剂的研制及工业放大[J].石油炼制与化工, 2005, 36(6):5-8 [85] 中国海洋石油总公司.一种改性氧化铝载体的制备方法: 中国, CN201611020927.7[P]. 2016-11-15. [86] 中国石油化工股份有限公司.一种球形改性氧化铝载体的制备方法: 中国, CN201510761748.8[P].. 2015-11-11. [87]牛国兴, 何坚铭, 陈晓银, 等.不同添加物和制备方式对热稳定性影响[J].催化学报, 1999, 20(5):535-540 [88]HORIUCHI T, TESHIMA Y, OSAKI T, et al.Improvement of thermalstability of alumina by addition of zirconia[J].Catalysis Letters, 1999, 62(2-4):107-111 [89]胡晓丽, 郑云弟, 梁顺琴, 等.选择性加氢催化剂载体氧化铝的热稳定性研究[J].石化技术与应用, 2011, 29(2):145-150 [90]孙利民, 梁顺琴, 王廷海, 等.磷改性氧化铝载体对碳四原料丁二烯选择加氢催化剂性能的影响[J].工业催化, 2011, 19(6):51-53 [91]Park S J, Cho J M, Ahn C I, et al..Roles of phosphorous-modified Al 2 O 3 for an enhanced stability of Co/Al 2 O 3 for CO hydrogenation to hydrocarbons[J].Journal of Molecular Catalysis A Chemical, 2017, 426(426):177-189 [92]WOO M H, CHO J M, JUN K W, et al.Thermally Stabilized Cobalt-Based Fischer-Tropsch Catalysts by Phosphorous Modification of Al2O3: Effect of Calcination Temperatures on Catalyst Stability[J].ChemCatChem, 2015, 7(9):1460-1469 [93] ZHENG X, CHEN X, CHEN J, et al.Synthesis and application of highly dispersed ordered mesoporous silicon-doped Pd-alumina catalyst with high thermal stability[J].Chemical Engineering Journal, 2016, 297(297):148-157 [94]温德荣, 喻正南, 梁相程, 等.助剂对含硅加氢处理催化剂性能的影响[J].工业催化, 2007, 15(11):31-34 [95]唐博合金, 王艾芬, 江政烨, 等.含硅氧化铝催化剂的制备及性质[J].上海工程技术大学学报, 2007, 21(4):326-330 [96]林磊, 王榕, 林炳裕, 等.用作催化剂载体的碳纳米管-氧化铝复合材料的制备[J].福州大学学报, 2009, 37(2):277-285 [97] 韩崇仁, 等.加氢裂化工艺与工程[M]. 北京: 中国石化出版社, 2001, 262. [98] 邵同培, 李高峰.FF-36、FC-50催化剂在柴油加氢改质装置的工业应用[J].炼油与化工技术, 2014, 19(5):67-71 [99]王峰, 杨运泉, 胡拥军, 等.催化剂的制备及其催化性能研究[J].现代化工, 2015, 35(10):66-70 [100]蒋永州, 陈博, 何林, 等.催化乙炔气相法合成醋酸乙烯初探[J].广东化工, 2010, 37(211):15-16 [101] SONG H, DAI M, GUO Y T, et al.Preparation of composite TiO2-Al2O3 supported nickel phosphide hydrotreating catalysis and catalytic activity for hydrodesulfurization of dibenzothiophene[J].Fuel Processing Technology, 2012, 96(96):228-236 [102] ORTEL E, POLTE J, BERNSMEIER D, et al.Pd/TiO2 coatings with template-controlled mesopore structure as highly active hydrogenation catalyst[J].Applied Catalysis A: General, 205, 493(493):25-32 [103]ZHAO Z X, XIA C G, XUE Q J, et al.Preparation,structure and properties of spherical SiO2-Al2O3 composites[J].Acta Physico-Chimica Sinca, 2007, 23(4):549-553 [104] LEE S W, PARAGUAY-DELGADO E., ARIZABALO R. D. Understanding the photophysical and surface properties of TiO2-Al2O3 nanocomposites[J].Materials Letters, 2013, 107(107):10-13 [105]XIAO X Q, SUN Q P, LIU F, et al.Synthesis and characterization of titanium-doped ordered mesoporous alumina[J].Chinese Journal of Structural Chemistry, 2014, 33(3):490-497 [106]胡品, 郭长友, 沈智奇, 等.载体表面钛改性对负载活性组分还原性能的影响[J].石油炼制与化工, 2014, 45(7):42-46 [107] FERDOUS D, BAKHSHI N N, DALAI A K, et al.Synthesis, characterization and performance of NiMo catalysts supported on titania modified alumina for the hydroprocessing of different gas oils derived from Athabasca bitumen[J].Applied Catalysis B: Environmental, 2007, 72(72):118-128 [108]HUANG W, DUAN A, ZHAO Z.Ti-modified alumina supports prepared by sol-gel method used for deep HDS catalysts[J].Catalysis Today, 2008, 131(1-4):314-321 [109]郑云弟, 李晓军, 王宗宝, 等.载体改性对重整预加氢催化剂性能的影响[J].现代化工, 2012, 32(2):48-51 [110]CHANG Q, ZHANG L, LIU X, et al.Preparation of crack-free ZrO2 membrane on Al2O3 support with ZrO2-Al2O3 composite intermediate layers[J].Journal of Membrane Science, 2005, 250(1-2):105-111 [111] 刘树信, 王海滨.氧化锆及掺杂氧化锆的研究进展[J].耐火材料, 2011, 45(3):209-213 [112]DAMYANOVA S, GRANGE P, DELMON B.Surface characterization of zirconia-coated alumina and silica carriers[J].Journal of Catalysis, 1997, 168(2):421-430 [113]IRIONDO A, BARRIO V L, CAMBRA J F, et al.Hydrogen production from glycerol over nickel catalysts supported on Al2O3 modified by Mg,Zr,Ce or La[J].Topics in Catalysis, 2008, 49(1-2):46-58 [114]SOISUWAN P, CHAMBERS D C, TRIMM D L, et al.Characteristics and catalytic properties of alumina–zirconia mixed oxides prepared by a modified Pechini method[J].Catalysis letters, 2005, 103(1-2):63-68 [115]许立信, 何潮洪, 朱明乔, 等.锆改性氧化铝负载的纳米金催化剂上环己烷氧化研究[J].高校化学工程学报, 2009, 23(2):309-313 [116]HU W, WANG Y, SHANG H Y, et al.Effects of Zr Addition on the Performance of the Pd-PtAl2O3 Catalyst for Lean-Burn Natural Gas Vehicle Exhaust Purification[J].Acta Physico-Chimica Sinica, 2015, 31(9):1771-1779 [117]KUNGUROVA O A, SHTERSER N V, GERASIMOV E Y, et al.Zr-P-modification of the gamma-Al2O3 support of cobalt-containing catalysts for the Fischer-Tropsch synthesis[J].Russian Chemical Bulletin, 2015, 64(4):825-834 [118]陈笃慧, 毛通双, 杨乐夫, 等.和+对提高六铝酸盐热稳定性燃烧活性的作用[J].天然气化工, 1996, 4(21):24-27 [119]朱警, 戴伟, 穆玮, 等.选择加氢催化剂载体氧化铝的改性及其工业应用[J].化工进展, 2004, 23(2):192-194 [120]王忠平, 傅骐.蒽醌法生产过氧化氢工作液体系和催化剂的改进[J].工业催化, 2004, 12(8):24-29 [121] 王忠平, 傅骐, 张瑜平.生产过氧化氢用的异型钯催化剂及其制备方法: 中国, 1562466A[P]. 2005-01-12. [122]JIAO Y, WANG J, QIN L, et al.Kerosene cracking over supported monolithic Pt catalysts: Effects of SrO and BaO promoters[J].Chinese Journal of Catalysis, 2013, 34(6):1139-1147 [123] BALLARINI A, BASILE F, BENITO P, et al.Platinum supported on alkaline and alkaline earth metal-doped alumina as catalysts for dry reforming and partial oxidation of methane [J].Applied Catalysis A: General, 2012, 433(433):1-11 [124]HE S N, CUI Y J, YAO Y L, et al.Effects of Alkaline Earth Metal on Performance of ZrO2-Al2O3 Support and Pd-Rh Close-Coupled Catalyst[J].Acta Physico-Chimica Sinica, 2011, 27(5):1157-1162 [125]SIRI GJ, BERTOLINI GR, CASELLA, ML, et al.PtSngamma-Al2O3 isobutane dehydrogenation catalysts: The effect of alkaline metals addition[J].Materials Letters, 2005, 59(18):2319-2324 [126]李燕秋, 贺振富, 李阳, 等.镧、铈载贵金属型汽车尾气净化催化剂中的作用[J].石油炼制与化工, 2004, 35(2):18-21 [127] 杨勇, 桓源峰, 曹敏.镧、锆改性的氧化铝载体对钯催化氧化甲烷活性的影响[J].化学研究, 2015, 26(3):292-297 [128]YAO W, LU G, GUO Y, et al.Promotional effect of Y2O3 on the performance of Agalpha-Al2O3 catalyst for epoxidation of propylene with molecular oxygen[J].Journal of Molecular Catalysis A: Chemical, 2007, 276(1-2):162-167 [129] OSORIO-VARGAS P, CAMPOS C H, NAVARRO R M, et al.Improved ethanol steam reforming on Rh/Al2O3 catalysts doped with CeO2 or/and La2O3: Influence in reaction pathways including coke formation[J].Applied Catalysis A: General, 2015, 505(505):159-172