非贵金属催化氢酰化反应研究进展

doi:10.12034/j.issn.1009-606X.217177

过程工程学报 ›› 2017, Vol. 17 ›› Issue (6): 1127-1133.DOI: 10.12034/j.issn.1009-606X.217177

非贵金属催化氢酰化反应研究进展

李婷^1,2，朱德萍^1,2，徐宝华^1,2*

1. 中国科学院过程工程研究所，北京 100190；2. 中国科学院大学化学与化工学院，北京 100049

收稿日期:2017-03-17 修回日期:2017-03-31 出版日期:2017-12-20 发布日期:2017-12-05
通讯作者: 徐宝华 bhxu@ipe.ac.cn
基金资助:
国家自然科学基金资助项目

Advances on Hydroacylation Reaction Catalyzed by First-row Transition Metals

Ting LI^1,2, Deping ZHU^1,2, Baohua XU^1,2*

1. Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China; 2. School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Received:2017-03-17 Revised:2017-03-31 Online:2017-12-20 Published:2017-12-05

摘要/Abstract

摘要： 近年来非贵金属因其地球丰度高、催化反应后处理方便等优点受到越来越多的关注，在某些领域取得了与贵金属相当的催化效果. 本工作主要概述了非贵金属在催化C X (X=C, O)氢酰化反应方面的研究进展，并展望了未来非贵金属催化氢酰化反应的研究方向. 非贵金属催化在底物适用性、反应活性、选择性及机理研究方面还面临着更多挑战.

关键词: 非贵金属催化, 氢酰化, C-H活化, 氧化环化

Abstract: Recently, the non-noble transition metals show an increasingly enormous application potential in homogeneous catalysis due to its relatively low cost and high abundance. And they are considered as promising catalysts which could serve as an alternative to the noble metals. The review summarizes the advances in hydroacylation, the addition of a formyl C?H bond across an unsaturated bond C X (X=C, O), catalyzed by first-row transition metals. And challenges focusing on scope of substrates, catalytic reactivity and selectivity, even the mechanism insight into the transformation are still worthy of exploration.

Key words: non-noble metal catalysis, hydroacylation, C-H activation, oxidative cyclization

李婷朱德萍徐宝华. 非贵金属催化氢酰化反应研究进展[J]. 过程工程学报, 2017, 17(6): 1127-1133.

Ting LI Deping ZHU Baohua XU. Advances on Hydroacylation Reaction Catalyzed by First-row Transition Metals[J]. Chin. J. Process Eng., 2017, 17(6): 1127-1133.

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非贵金属催化氢酰化反应研究进展

Advances on Hydroacylation Reaction Catalyzed by First-row Transition Metals

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