La掺杂ZnO的制备及其光催化降解孔雀石绿

doi:10.12034/j.issn.1009-606X.217436

过程工程学报 ›› 2018, Vol. 18 ›› Issue (4): 828-833.DOI: 10.12034/j.issn.1009-606X.217436

La掺杂ZnO的制备及其光催化降解孔雀石绿

田志茗*，王鑫月

齐齐哈尔大学化学与化工学院，黑龙江齐齐哈尔 161006

收稿日期:2017-12-28 修回日期:2018-01-12 出版日期:2018-08-22 发布日期:2018-08-15
通讯作者: 王鑫月 1594917000@qq.com
基金资助:
黑龙江省教育厅基本科研业务专项课题;齐齐哈尔市科学技术局项目

Synthesis of La-doped ZnO and its photocatalytic degradation to malachite green

Zhiming TIAN?, Xinyue WANG

College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China

Received:2017-12-28 Revised:2018-01-12 Online:2018-08-22 Published:2018-08-15

摘要/Abstract

摘要： 采用溶胶?凝胶法制备了不同La掺杂量的La/ZnO催化剂，分析了其组成和性质，以孔雀石绿溶液为染料模型，研究了催化剂的光催化降解性能. 结果表明，ZnO为六角纤锌矿结构，La3+以小La2O3簇的形式均匀分布在ZnO纳米颗粒上. 摩尔比La:Zn=0.05时La/ZnO具有良好的催化活性，用300 W汞灯照射2 h，孔雀石绿的降解率可达98.8%，300 W氙灯照射2 h降解率达90.4%，比ZnO的降解率提高了51.2%.

关键词: La掺杂ZnO, 光催化降解, 孔雀石绿

Abstract: La/ZnO catalysts with different La doping amounts were prepared by sol?gel method. The microstructures and properties of La/ZnO were characterized. Using malachite green solution as the dye model, the photocatalytic degradation of the catalyst was studied. The results indicated that ZnO was hexagonal wurtzite structure, and La3+ was uniformly distributed on the ZnO nanoparticles in the form of small La2O3 clusters. La/ZnO had good catalytic activity when the molar ratio of La:Zn=0.05. The degradation rate of malachite green reached 98.8% within 2 h under 300 W mercury lamp illumination. The degradation rate up to 90.4% under 300 W xenon lamp irradiation 2 h, increased by 51.2% than ZnO due to La doping.

Key words: La-doped ZnO, photocatalytic degradation, malachite green

田志茗王鑫月. La掺杂ZnO的制备及其光催化降解孔雀石绿[J]. 过程工程学报, 2018, 18(4): 828-833.

Zhiming TIAN Xinyue WANG. Synthesis of La-doped ZnO and its photocatalytic degradation to malachite green[J]. Chin. J. Process Eng., 2018, 18(4): 828-833.

参考文献

[1]张中领, 孙晓玲.染料废水处理技术现状与发展[J].资源与环境, 2017, 43(7):205-205 [2]Zhang Z L, Sun X L.Present Situation and Development of Dye Wastewater Treatment Technology[J].Resources and Environment, 2017, 43(7):205-205 [3] 梁婉婷, 田鹏, 张洪波.染料废水的处理方法研究[J].山东化工, 2017, (46):152-155.[J].山东化工, 2017, 46:152-155 [4]Liang W T, Tian P, Zhang H B.Study on the Treatment of Dye Wastewater[J]. Shan Dong Chemical Industry, 2017, (46):152-155.[J].Shan Dong Chemical Industry, 2017, 46:152-155 [5] 王震.新型可见光催化剂的制备及其性能研究[D].浙江大学, 2014. 3-11. [6]Wang Z.The Preparation and Photocatalvtic study of Novel Visible-light Photocatalvsts[D]. Zhe Jiang University, 2014. 3-11. [7]赵燕茹.可见光响应型基纳米复合光催化材料的研究进展[J].材料工程, 2017, 45(6):129-137 [8]Zhao Y R.Research Progress on Visible-light Responding ZnO-based Nanocomposite Photocatalyst[J].Journal of Materials Engineering, 2017, 45(6):129-137 [9]Xiaoqing Chen, Zhansheng Wu, Dandan Liu, et, al.Preparation of ZnO Photocatalyst for the Efficient and Rapid Photocatalytic Degradation of Azo Dyes[J].Nanoscale Research Letters, 2017, 12(143):2-10 [10]Jin-jin Ban, Guan-cheng Xu, et, al.Mesoporous ZnO microcube derived from a metal organic framework as photocatalyst for the degradation of organic dyes[J].Journal of Solid State Chemistry, 2017, 2(256):151-157 [11]Maryam Moradi, Mohammad Haghighi, Somaiyeh Allahyari.Precipitation Dispersion of Ag-ZnO Nanocatalyst over Functionlized Multiwall Carbon Nanotube Use in Degradation of Acid Orange from Wastewater[J].Accepted Manuscript, 2017, 10(1):1-41 [12] 关卫省, 宋优男, 霍鹏伟, 等.过渡金属掺杂ZnO纳米光催化剂对四环素的光催化降解[J] .安全与环境学报, 2012, 06:57-61．[J].安全与环境学报, 2012, (06):57-61 [13]Guan W S, Song Y N, Huo P W, et, al.Effects of transition metal doping on the ZnO photocatalytic degradation of the tetracycline [J]. Journal of Safety and Environment, 2012, (06):57-61．[J].Journal of Safety and Environment, 2012, (06):57-61 [14] Clament Stagaya, Selvamn, Narayanans, et, al.Pure and Mg-doped self-assembled ZnO nanoparticles for the enhanced photocatalytic degradation of 4-chlorophenol [J].Jouranal of Environmental Science, 2013, (10):2157-2167.[J].Jouranal of Environmental Science, 2013, 10:2157-2167 [15] 曹宇.稀土元素掺杂纳米ZnO功能材料的制备及性能研究[D].沈阳工业大学, 2017. 5. [16]Cao Y.Preparation and Optical Properties Reserch on rare earth element doped nanostructured ZnO[D]. Shen Yang University of Technology. 2017. 5. [17]蒋彩娜, 王国方, 周立亚.碳掺杂的制备及其光催化性能[J].桂林理工大学学报, 2017, 37(2):316-321 [18]Jiang C N, Wang G F, Zhou L Y.Preparation and photocatalytic properties of ZnO doped with carbon[J].Journal of Guilin University of Technology, 2017, 37(2):316-321 [19] 曲华.SnO2改性纳ZnO光催化降解NPE-10［J］.兰州大学学报(自然科学版), 2012, 05:139-144.[J].兰州大学学报自然科学版）, 2012, (05):139-144 [20]Qu H.SnO2 modified nano-ZnO photocatalyst and its catalytic performance for degradation of noylphenool ethoxylate-10[J]. Journal of Lanzhou University(Natural Science), 2012, 05:139-144.[J].Journal of Lanzhou University(Natural Science), 2012, (05):139-144 [21]Balu, Krishnakumar, Avula, et, al.Solar and visible active amino porphyrinSiO2-ZnO for the degradation of naphthol blue black[J].Acceoted Manuscript, 2017, 10(1016):1-13 [22]刘玮洁, 孙正昊, 黄宇欣, 等.不同价态稀土元素掺杂的电子结构和光学性质[J].物理学报, 2013, 62(12):1-7 [23]Liu Y J, Sun Z H, Haung Y, et, al.Electronic structures and optical properties of rare earth element (Yb) with different valences doped in ZnO[J]. Acta Phys. Sin. 2013, 62(12):1-7.[J].Acta Phys. Sin., 2013, 12(62):1-7 [24]Rosalin Beura, R Pachaiappan, P Tangadurai.A detailed study on the Sn4+ doped ZnO for enhanced photocatalytic degradation[J].Applied Surface Science, 2017, 2(433):887-898 [25]Zheng Xing, Yanfeng Chen, Cuiyin Liu, et, al.Synthesis of core-shell ZnOoxygen dope g-C3N4 visible light driven photocatalyst via hydrothermal method[J].Journal of Alloys and Compounds, 2017, 25(708):853-861 [26] 谭东.稀土元素的特征和用途(上)[J].广西化工, 1990(1)：2-7.[J].广西化工, 1990, 1:2-7 [27]Tan D.Characteristics and Uses of Rare Earth Elements (Ⅰ)[J]. Guangxi Chemical Industry, 1990(1)：2-7.[J].Guangxi Chemical Industry, 1990, 1:2-7 [28]A Manikanda, E Manikanda, B Meenatchi, et al.Rare element (REE) lanthanum doped zinc oxide (La:ZnO)nanomaterials:Synthesis structural optical and antibacterial studies[J].Accept Manauscript, 2017, 06(336):1-28 [29] 王晓月.新型纳米?La2O3/AAO催化剂的制备研究[D].长春工业大学, 2016.21-23. [30]Wang X Y.Study on the Preparation of Novel La2O3/AAO Nanoarray Catalyst[D]. Chang Chun University of Technology, 2016.21-23. [31]Viet Ha-Tran, Thi, Byeong-Kyu, Lee.Effective photocatalytic degradation of paracetacamol using La-doped ZnO photocatalyst under visible light irradiation[J].Accepted Manuscript, 2017, 10(1016):1-32 [32]Tiekun Jia, Weimin Wang, Fei Long, et, al.Fabrication,Characterization and photocatalytic activity of La-doped ZnO nanowires[J].Journal of Alloys and Compounds, 2009, 10(484):410-415 [33]Tingting WU, Yonghong Ni, Xiang MA, et, al.La-doped ZnO nanoparticles:Simple solution combusting preparation and applications in the wastewater treatment[J].Accepted Manuscript, 2013, 8(18):1-20 [34]Ivan Mouritys, Pereria Silva, Gabriela Byzynski, et, al.Different dye degradation mechanisms for ZnO and ZnO doped with N(ZnO:N)[J].Accepted Manuscript, 2016, 16(1169):1-38

La掺杂ZnO的制备及其光催化降解孔雀石绿

Synthesis of La-doped ZnO and its photocatalytic degradation to malachite green

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