Cu2+对磁化蒸馏水改善辉钼矿浮选效果的影响

doi:10.12034/j.issn.1009-606X.219198

过程工程学报 ›› 2020, Vol. 20 ›› Issue (3): 332-337.DOI: 10.12034/j.issn.1009-606X.219198

Cu²⁺对磁化蒸馏水改善辉钼矿浮选效果的影响

荀婧雯¹，王宇斌^1*，汪潇²，王真¹，王妍¹

1. 西安建筑科技大学资源工程学院，陕西西安 710055 2. 河南城建学院材料与化工学院，河南平顶山 467036

收稿日期:2019-04-29 修回日期:2019-07-10 出版日期:2020-03-22 发布日期:2020-03-20
通讯作者: 荀婧雯 405248370@qq.com
基金资助:
国家自然科学基金项目

Effect of Cu²⁺ on improvement of molybdenite floatability in magnetized distilled water

Jingwen XUN¹, Yubin WANG^1*, Xiao WANG², Zhen WANG¹, Yan WANG¹

1. School of Resources Engineering, Xi?an University of Architecture＆Technology, Xi?an, Shaanxi 710055, China 2. College of Material & Chemical Engineering, Henan University of Urban Construction, Pingdingshan, Henan 467036, China

Received:2019-04-29 Revised:2019-07-10 Online:2020-03-22 Published:2020-03-20

摘要/Abstract

摘要： 通过单矿物浮选实验、Zeta电位测试及X射线光电子能谱(XPS)、扫描电子显微镜(SEM)和能谱(EDS)分析，研究了Cu2+对磁化蒸馏水改善辉钼矿浮选效果的影响。结果表明，用磁化蒸馏水浮选时，在煤油用量160 mg/L及2＃油用量80 mg/L的条件下，Cu2+浓度为320 mg/L时辉钼矿回收率可达83.06%，比Cu2+浓度为0时的回收率增加了3.14个百分点，Cu2+对磁化蒸馏水改善辉钼矿浮选效果的影响较小。Cu2+和Cu(OH)+吸附在辉钼矿表面使其Zeta电位正向增大，有利于煤油在辉钼矿表面的吸附。辉钼矿表面上吸附的Cu2+和Cu(OH)+与溶液中的MoO42?反应生成CuMoO4沉淀并覆盖在辉钼矿断裂面上，抑制了辉钼矿断裂面中钼元素和硫元素的氧化反应及氧化钼溶解，最终对磁化蒸馏水改善辉钼矿浮选效果有积极影响。

关键词: 磁化蒸馏水, 辉钼矿, 铜离子, 改善效果, 适应性

Abstract: Magnetized water can improve the flotation behaviors of sulfide minerals such as molybdenite effectively, but the beneficiation index was unstable in flotation process of molybdenite by use of magnetized water. In order to investigate the effect of Cu2+ on the improvement molybdenite floatability in magnetized distilled water, different samples were characterized by means of the flotation test of pure molybdenite, Zeta potential, X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) and energy dispersive spectrometer (EDS). The results showed that the floatability of molybdenite in magnetized distilled water was improved with the addition of copper ion when the amount of kerosene was 160 mg/L and the amount of 2# oil was 80 mg/L. Furthermore, the molybdenite recovery rate reached 83.06% when the concentration of dissolved copper ion in magnetized distilled water was 320 mg/L. Compared with Cu2+ concentration of 0 mg/L, the flotation recovery rate of molybdenite increased by 3.14 percentage point. The Zeta potential of molybdenite in magnetized distilled water obviously increased positively direction because Cu2+ and Cu(OH)+ adsorbed on the surface of molybdenite. The Zeta potential of molybdenite increased with the increase of copper ions dosage which was beneficial to the adsorption of kerosene on molybdenite surface in local positive charge. The Cu2+ and Cu(OH)+ adsorbed on the fracture surface of molybdenite interacted with MoO42? in magnetized distilled water formed copper molybdate which covered on molybdenite surface, which decreased amount and reaction probability of reactive molybdenum and sulfur on molybdenite surface then inhibited the oxidation of molybdenum and sulfur elements on molybdenite fracture surface and the dissolution reaction of molybdenum oxide into solution. Therefore it highly improved the flotation behaviors of molybdenite. This work provided a certain theoretical basis for improving the flotation efficiency of molybdenite with magnetized water, and it also provided some degree of reference for the application of magnetized water in the process of ore.

Key words: magnetized distilled water, molybdenite, copper ion, improvement effect, adaptability

荀婧雯王宇斌汪潇王真王妍. Cu²⁺对磁化蒸馏水改善辉钼矿浮选效果的影响[J]. 过程工程学报, 2020, 20(3): 332-337.

Jingwen XUN Yubin WANG Xiao WANG Zhen WANG Yan WANG. Effect of Cu²⁺ on improvement of molybdenite floatability in magnetized distilled water[J]. Chin. J. Process Eng., 2020, 20(3): 332-337.

参考文献

[1]黄向阳，王中海，罗小苟，等.磁浮选技术在选矿中的应用[J].矿业快报, 2007, 05:84-85+90. [2]Huang X Y, Wang Z H, Luo X G, et al.The Application of Magnetic Treatment Technique on Flotation[J]., 2007, 05:84-85+90. [3]陈锋，张忠辉，张艮林，等.选矿中磁处理技术研究现状[J].现代矿业, 2010, 26(02):22-24 [4]Chen F, Zhang Z H, Zhang K L, et al.Research on Situation of Magnetic Treament Technology of Mining[J].Modern Min-ing, 2010, 26(02):22-24 [5]邹健.磁化浮选的发展与探讨[A].中国钢铁年会论文集.北京, 1997:1. [6]Zou J.Development and Investigation of Magnetic Flotation[A].Proceedings of China Iron & Steel Annual Meeting.Beijing, 1997:1. [7]朱巨建，李晓安，陈炳辰.磁化处理技术的发展及其在矿物浮选中的应用[J], 1997(03):52-56.[J].国外金属矿山, 1997, 03:52-56 [8]Zhu J J, Li X A, Chen B C.The Development and Application of Magnetic Treatment Technique on Flotation[J]., 1997, 03:52-56 [9]杨益彬.磁化处理技术在矿物加工中的应用[J].能源与节能, 2018(06):126-127. [10]Yang Y B.Application of Magnetization Treatment Technology in Mineral Processing[J]. Energy and Energy Conserva-tion, 2018(06):126-127. [11]邱廷省，崔立凤，方夕辉.磁处理技术在矿物加工中的应用研究进展[J].金属矿山, 2008(12):1-4+8 [12]Qiu T S, Cui LF, Fang X H.Progress in the Application Research of Magnetic Treatment Technology in Mineral Processing[J]. Metal Mine, 2008(12):1-4+8. [13]徐秋生.磁化烃油选钼试验研究[J].金属矿山, 2006(09):53-54. [14]Xu Q S.Research on Hydrocarbon Oil Magnetization for Molybdenum Separation[J]. Metal Mine, 2006(09):53-54. [15]邱廷省，崔立凤，方夕辉.磁化对浮选药剂及浮选过程的影响[J].中国有色金属学报, 2009, 19(07):1338-1344 [16]Qiu T S, Cui L F, Fang X H.Effect of magnetization on flotation reagents and process[J].The Chinese Journal of Nonferrous Met-als, 2009, 19(07):1338-1344 [17]黄向阳.水系磁处理在硫化铜矿浮选过程中的影响研究[D].江西：江西理工大学, 2008. [18]Huang X Y.The Influence about Sulfide Copper Flotation by magnetization [D]. Jiangxi：Jiangxi University of science and tech-nology, 2008. [19]边炳鑫，陈清如，韦鲁滨.浮选矿浆的磁化处理效应和机理研究[J].煤炭学报, 2004(01):97-100. [20]Bian B X, Chen Q R, Wei L B.Study on Flotation pulp’s Magnetization Effect and Mechanism[J]. Journal of China Coal Socie-ty, 2004(01):97-100. [21]边炳鑫，陈清如，韦鲁滨.药剂磁化处理对煤泥浮选效果影响的研究[J].中国矿业大学学报, 2004(03):109-112. [22]Bian B X, Chen Q R, Wei L B.Research on Coal Slime Flotation Using Magnetized Agents[J]. Journal of China University of Min-ing& Technology, 2004(03):109-112. [23]王真，何廷树，王宇斌，等.磁化水改善钼粗选作业回收率试验研究[J].矿业研究与开发, 2018, 38(09):72-74 [24]Wang Z, He T S, Wang Y B, et al.Experimental Study on Magnetized Water Improving the Recovery Rate of Molybdenum by Roughing[J].Mining Research and Development, 2018, 38(09):72-74 [25]何廷树，石旭，李慧，等.磁化改性煤油对洛阳某钼矿石低温浮选指标的影响[J].金属矿山, 2017(06):99 -103. [26]He T S, Shi X, Li H, et al.Influence of Magnetized Kerosene on Flotation Index of Molybdenum Ore from Luoyang at Low Tem-perature[J]. Metal Mine, 2017(06):99 -103. [27]魏桢伦, 李育彪.辉钼矿晶面各向异性及其对浮选的影响机制[J].矿产保护与利用, 2018(03):31-36. [28]Wei Z L, Li Y B.Anisotropy of Molybdenite Surface and Its Effects on Flotation Mechanism[J]. Conservation and Utilization of Mineral Resources, 2018(03):31-36. [29]崔林, 李锐.光电子能谱在选矿工艺矿物学上的应用[J].化工矿山技术, 1987(04):26-31. [30]Cui L, Li R.Application of X-ray photoelectron spectroscopy on Technological Mineralogy of Beneficiated Products[J]. Industrial Minerals & Processing, 1987(04):26-31.

Cu²⁺对磁化蒸馏水改善辉钼矿浮选效果的影响

Effect of Cu²⁺ on improvement of molybdenite floatability in magnetized distilled water

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