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过程工程学报 ›› 2023, Vol. 23 ›› Issue (8): 1137-1149.DOI: 10.12034/j.issn.1009-606X.222314CSTR: 32067.14.jproeng.222314

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生物基材料核心单体分离纯化技术研究进展

王坤1,2， 纪秀玲2， 蔺琨2， 黄玉红2,3*   

  1. 1. 郑州大学河南先进技术研究院，河南 郑州 450000 2. 中国科学院过程工程研究所，离子液体清洁过程北京市重点实验室，北京 100190 3. 郑州中科新兴产业技术研究院，河南 郑州 450000
  • 收稿日期:2022-08-29 修回日期:2022-11-30 出版日期:2023-08-28 发布日期:2023-09-01
  • 通讯作者: 黄玉红 yhhuang@ipe.ac.cn
  • 基金资助:
    国家自然科学基金项目;北京市科技新星;北京市科技新星;中科豫能绿色过程联合研发中心科研项目;中国科学院绿色过程制造创新研究院自主部署联合基金项目

Research progress of core monomer separation and purification technology for bio-based materials

Kun WANG1,2,  Xiuling JI2,  Kun LIN2,  Yuhong HUANG2,3*   

  1. 1. Henan Institute of Advanced Technology, Zhengzhou University, Zhengzhou, Henan 450000, China 2. Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China 3. Zhengzhou Institute Emerging Industry Technology, Zhengzhou, Henan 450000, China
  • Received:2022-08-29 Revised:2022-11-30 Online:2023-08-28 Published:2023-09-01

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摘要： 石化基材料生产消耗大量不可再生资源，并对环境造成一定程度污染。而利用可再生资源生产的生物基材料性能可以与石化基材料相媲美，符合绿色、低碳、环保的发展理念，为实现“碳达峰、碳中和”的目标提供强有力的技术支撑。近年来，随着国内外政策对生物基材料的支持，生物基材料已成为国内外争相发展的新材料，为生物基材料行业的发展提供了良好的契机。利用生物法生产的生物基材料核心单体具有生产条件温和、价格低廉、绿色环保等优点，但发酵液内成分复杂以及单体浓度偏低，导致分离难度增加，严重制约了生物基材料整个行业的发展。生物基材料生产要求单体纯度高，少量杂质会影响生物基材料的外观性能。现有的生物基材料核心单体的分离研究及应用中，充分发挥化工分离技术的优势，开发出了获得高纯度生物基材料核心单体的分离纯化工艺。本综述介绍了生物基材料的生产现状，综述了近年来几种应用广泛的生物基材料核心单体分离纯化技术的研究进展，分析了目前分离技术的优缺点，最后对生物基材料核心单体分离纯化技术的发展趋势进行了展望。

关键词: 生物基材料, 核心单体, 发酵液, 分离纯化

Abstract: The production of petrochemical-based materials consumes large amounts of non-renewable resources and cause a certain degree of pollution to the environment. The performance of bio-based materials produced by renewable resources can be comparable to that of petrochemical based materials, which is in line with the development concept of green, low-carbon and environmental protection, and provides strong technical support for the realization of the goal of carbon peaking and carbon neutrality. In recent years, with the domestic and international policies tilted to the bio-based materials industry, bio-based materials have become a new material for domestic and international development, providing a good opportunity for the development of bio-based materials industry. The core monomer of bio-based materials produced by biological method has the advantages of mild production conditions, low price, and green environmental protection. But the complex composition within the fermentation broth as well as the low concentration of monomers and the difficulty of separation have seriously restricted the development of the whole industry of bio-based materials. The production of bio-based materials requires high-purity monomers, and a small amount of impurities affect the appearance and performance of bio-based materials. The existing research and application of separation of core monomers of bio-based materials has developed the process of obtaining high purity separation and purification of core monomers of bio-based materials by taking full advantage of chemical separation technology. This review briefly introduces the current status of the production of bio-based materials, reviews the research progress of several widely used separation and purification technologies for core monomers of bio-based materials in recent years, analyzes the advantages and disadvantages of current separation technologies. Finally providing an outlook on the development trend of separation and purification technologies for core monomers of bio-based materials.

Key words: Bio-materials, Core monomer, fermentation broth, separation and purification