欢迎访问过程工程学报, 今天是

过程工程学报 ›› 2024, Vol. 24 ›› Issue (6): 746-752.DOI: 10.12034/j.issn.1009-606X.223075

• 研究论文 • 上一篇    

Li0.98Ca0.02Mn2O4的制备及其电化学性能

申明思， 袁海波， 张豆豆， 王京， 钮高田， 马扬洲， 孙雅馨*   

  1. 安徽工业大学材料科学与工程学院，安徽 马鞍山 243002
  • 收稿日期:2023-03-21 修回日期:2023-11-13 出版日期:2024-06-28 发布日期:2024-06-26
  • 通讯作者: 孙雅馨 syaxin@ahut.edu.cn
  • 基金资助:
    富锂锰基正极材料的无序结构设计及储锂性能研究;复合改性的锰酸镁及其在水系镁离子电池中的应用研究

Preparation and electrochemical properties of Li0.98Ca0.02Mn2O4

Mingsi SHEN,  Haibo YUAN,  Doudou ZHANG,  Jing WANG,  Gaotian NIU,  Yangzhou MA,  Yaxin SUN*   

  1. School of Materials Science and Engineering, Anhui University of Technology, Ma'anshan, Anhui 243002, China
  • Received:2023-03-21 Revised:2023-11-13 Online:2024-06-28 Published:2024-06-26

RichHTML

PDF

摘要： 本工作采用水热结合后续高温煅烧法制备单相的尖晶石型结构Li0.98Ca0.02Mn2O4。结果表明，Li0.98Ca0.02Mn2O4晶粒形成的小团聚体内有孔型通道，利于与电解液有效接触，增加正极材料的活性位点，有效缩短了Li+的扩散路径。电化学性能表明，Li0.98Ca0.02Mn2O4呈现出优异的倍率性能，并且在1 C的电流密度下，初始放电容量为117.5 mAh/g，是未掺杂LiMn2O4样品的1.4倍，150圈循环后，容量保持率为80%，1000圈循环后，仍可保持60%的容量。Ca掺入晶格后，使晶格膨胀，有利于提高Li+的扩散能力；经计算，Li0.98Ca0.02Mn2O4样品的扩散系数为2.5×10-11 cm2/s，约为未掺杂LiMn2O4样品的1.6倍。

关键词: LiMn2O4, Ca掺杂, 循环性能, 扩散系数

Abstract: Many research focus on improving the electrochemical properties of LiMn2O4 by chemical doping method. In cubic spinel structure LiMn2O4, the diversity of doping elements and doping positions provides a wide space for improving performance. Doping at the 16d octahedral position occupied by Mn can effectively suppress the Jahn-Teller effect and maintain the stability of the structure. By comparison, using elements with large ion radius to dope at the 8a tetragonal position occupied by Li can enlarge the Li+ diffusion channel and enhance the kinetics diffusion coefficient. In this work, pure phase of Li0.98Ca0.02Mn2O4 was successfully synthesized using the hydrothermal method followed by annealing at 750℃ for 5 h. The crystal structures and the morphologies of the products were analyzed by powder X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). The electrochemical properties were characterized by galvanostatic charge/discharge experiments and electrochemical impedance spectroscope (EIS) tests. XRD analysis showed that the lattice constant increased by 0.12% in Ca-doped LiMn2O4 and the expansion of the crystal cell was beneficial to improving the diffusion of Li+. The small aggregates with porous channels formed by stacking nanoparticles were observed by FESEM. The results showed that Li0.98Ca0.02Mn2O4 exhibited the excellent rate capability with the larger discharge capacity at the relatively current rate range of 0.5 C~5 C. Especially, at 0.5 C, Li0.98Ca0.02Mn2O4 delivered the first discharge capacity of 126 mAh/g, which was 17.8% higher than that of undoped LiMn2O4 samples. The capacity retention of both samples was maintained at about 88.8% after 50 cycles. At 1 C, Li0.98Ca0.02Mn2O4 still holded its high discharge capacity of 117.5 mAh/g and capacity retention of 90% after 50 cycles, 80% after 150 cycles, and 60% after 1000 cycles. Undoped LiMn2O4 sample had low capacity of 57.0 mAh/g, but the capacity retention reacheed 67% after 1000 cycles, indicating good cycle stability. The calculated kinetics diffusion coefficient of Li0.98Ca0.02Mn2O4 was 2.5×10-11 cm2/s, which was about 1.6 times of undoped sample.

Key words: LiMn2O4, Ca doping, cycle properties, diffusion coefficient