欢迎访问过程工程学报, 今天是

›› 2009, Vol. 9 ›› Issue (4): 676-682.

• 反应与分离 • 上一篇    下一篇

镍钴锰三元电池废料浸出液除铜铁净化

李金辉 李新海 周友元 胡启阳 符芳铭 张琏鑫 张明   

  1. 中南大学冶金科学与工程学院 中南大学冶金科学与工程学院 中南大学冶金科学与工程学院 中南大学冶金科学与工程学院 中南大学冶金科学与工程学院 中南大学冶金科学与工程学院 山东理工大学化学工程学院
  • 收稿日期:2009-02-19 修回日期:2009-03-26 出版日期:2009-08-20 发布日期:2009-08-20
  • 通讯作者: 李金辉

Purification of Leaching Solution of Spent NixCoyMnz Battery Material by Removing Cu and Fe

LI Jin-hui, LI Xin-hai, ZHOU You-yuan, HU Qi-yang, ZHANG Ming, ZHANG Lian-xin ZHANG Ming   

  1. School of Materials and Chemical Engineering , Jiangxi University of Science and Technology School of Metallurgy Science and Engineering , Central South University School of Metallurgy Science and Engineering , Central South University School of Metallurgy Science and Engineering , Central South University School of Metallurgy Science and Engineering , Central South University School of Metallurgy Science and Engineering , Central South University
  • Received:2009-02-19 Revised:2009-03-26 Online:2009-08-20 Published:2009-08-20
  • Contact: LI Jin-hui,

PDF

摘要： 对镍钴锰三元废电池材料盐酸浸出液分离去除铜和铁杂质进行了研究. 采用铁粉置换法除铜，考察了铁粉用量、反应温度和反应时间等因素对铜脱除率及镍钴锰损失率的影响；除铜后浸出液采用针铁矿法除铁，考察了反应时间、反应温度及终点pH值对铁去除率和镍钴锰损失率的影响. 结果表明，铜和铁的去除率均在99%以上，镍、钴、锰的总损失率分别为2%, 3%, 2%. 净化后溶液满足制备合格镍钴锰三元系前驱体的要求.

关键词: 电池废料, 镍, 钴, 回收, 浸出, 净化

Abstract: The removal of copper and iron impurities from leaching solution of NixCoyMnz spent battery material is studied. The copper is removed through replacement by iron powder, while the effects of Fe powder amount, reaction time and reaction temperature on the copper removal and loss of nickel, cobalt and manganese are examined. And the iron is removed by precipitation in the copper removed solution, while the conditions of pH value, reaction time and reaction temperature are discussed, which can influence the iron removal and the loss of nickel, cobalt and manganese. The result shows that Cu and Fe can be removed 99% at least. And at the same time, the loss rates of Ni, Co and Mn are about 2%, 3% and 2%, respectively. The leaching solution after purification accords with the demand of preparation of NixCoyMnz ternary system precursor.

Key words: spent battery material, nickel, cobalt, recovery, leaching, purification

中图分类号: