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过程工程学报 ›› 2025, Vol. 25 ›› Issue (6): 635-644.DOI: 10.12034/j.issn.1009-606X.224256

• 研究论文 • 上一篇    

界面改性橡胶粉/铁尾矿基混凝土制备与性能研究

胡义明1,3， 黄洋1， 王超2， 陈洲3， 杨婷3， 高翔鹏1， 李明阳1*   

  1. 1. 安徽工业大学冶金工程学院，安徽 马鞍山 243032 2. 中铝科学技术研究院有限公司，北京 102209 3. 中钢集团马鞍山矿山研究总院股份有限公司，安徽 马鞍山 243000
  • 收稿日期:2024-08-16 修回日期:2024-12-25 出版日期:2025-06-28 发布日期:2025-07-01
  • 通讯作者: 李明阳 myl.ahut@foxmail.com
  • 基金资助:
    “十四五”国家重点研发计划资助项目;安徽省高等学校科学研究重点项目;金属矿山安全与健康国家重点实验室开放课题

Preparation and performance study of surface-modified rubber powder/iron tailings-based concrete

Yiming HU1,3,  Yang HUANG1,  Chao WANG2,  Zhou CHEN3,  Ting YANG3,  Xiangpeng GAO1,  Mingyang LI1*   

  1. 1. School of Metallurgical Engineering, Anhui University of Technology, Ma'anshan, Anhui 243032, China 2. Chinalco Research Institute of Science and Technology Co., Ltd., Beijing 102209, China 3. SINOSTEEL Maanshan General Institute of Mining Research Co., Ltd., Ma'anshan, Anhui 243000, China
  • Received:2024-08-16 Revised:2024-12-25 Online:2025-06-28 Published:2025-07-01

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摘要： 本工作以废弃轮胎制成橡胶粉掺入铁尾矿和水泥中制作出铁尾矿基橡胶混凝土(ITRC)，研究了橡胶粒度、浸泡药剂、硅烷偶联剂接枝对ITRC的流动性、抗压强度、抗折强度和折压比的影响，并通过微观形貌分析探究了橡胶粉改性对ITRC的作用机理。结果表明，橡胶粉经过酸性KMnO4溶液浸泡，再进行硅烷接枝处理，可以明显提高橡胶粉与ITRC界面的相容性及黏结效果，减少基体微观裂缝的产生；在铁尾矿和水泥质量分数比为82∶18、改性60目(250 μm)橡胶粉掺量1wt%、水灰比18%的情况下，ITRC的28 d抗压强度达到32.8 MPa，抗折强度达到5.1 MPa，相较于纯铁尾矿水泥材料，抗压强度提高28.6%，抗折强度提升21.4%。本工作可为铁尾矿和废弃轮胎的资源化利用提供参考，有助于加速固体废弃物的循环利用。

关键词: 铁尾矿, 废弃轮胎, 界面改性, 橡胶混凝土, 资源循环

Abstract: In this study, a new type of construction material, iron tailings-based rubber concrete (ITRC), was innovatively prepared from waste tire rubber powder and iron tailings. The effects of rubber particle size, soaking agent usage, and silane coupling agent grafting on the fluidity, compressive strength, flexural strength, and flexural-compression ratio of ITRC were investigated in depth. The intrinsic mechanism of rubber powder on the improvement of ITRC properties was revealed by advanced analytical techniques such as micromorphology analysis. It was found that pre-soaking of rubber powder in acidic potassium permanganate (KMnO4) solution followed by silane coupling agent treatment significantly improved the compatibility and bonding effect at the interface between the rubber powder and ITRC, and effectively reduced the generation of microcracks in the matrix. Under the condition of an 82∶18 mass ratio of iron tailings to cement, 1wt% rubber powder doping, and an 18% water-to-cement ratio, the 28 day compressive strength of ITRC reached 32.8 MPa, and the flexural strength reached 5.1 MPa, which increased the compressive strength by 28.6% and the flexural strength by 21.4% compared with that of pure iron tailings cement material. This study not only provided a scientific basis for the recycling of iron tailings and waste tires but also provided a new idea for the accelerated recycling of solid waste. The research results helped to promote the development of environmentally friendly building materials, promoted the recycling of resources, and were of great significance in realizing the green transformation of the construction industry. Through this study, it could be seen that waste materials could be transformed into new materials with practical value through scientific methods and innovative technologies, which not only reduced environmental pollution but also opened up a new way for the sustainable use of resources. The successful preparation and optimization of the properties of ITRC demonstrated the possibility of realizing the dual goals of waste utilization and environmental protection in the construction field. This research result had important theoretical and practical value for promoting the sustainable development of the building materials industry.

Key words: iron tailings, waste tires, interface modification, rubber concrete, resource recycling