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过程工程学报 ›› 2020, Vol. 20 ›› Issue (11): 1289-1295.DOI: 10.12034/j.issn.1009-606X.219368

• 反应与分离 • 上一篇    下一篇

载铜树脂处理高含盐氨氮废水的性能

殷若愚， 陈云嫩*， 何彩庆， 刘 晨   

  1. 江西理工大学江西省矿冶环境污染控制重点实验室，江西 赣州 341000
  • 收稿日期:2019-12-09 修回日期:2020-03-05 出版日期:2020-11-22 发布日期:2020-11-20
  • 通讯作者: 殷若愚 314269640@qq.com
  • 基金资助:
    过渡金属离子与高分子载体、氨配体间空间匹配及其在高含盐氨氮废水处理中应用(51864021);催化臭氧氧化/沉淀耦合技术处理钨冶炼废水中典型无机污染物的系统优化

Treatment performance of ammonia-nitrogen wastewater containing high salt by copper-loaded resin

Ruoyu YIN, Yunnen CHEN*, Caiqing HE, Chen LIU   

  1. Jiangxi Key Laboratory of Mining & Metallurgy Environmental Pollution Control, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China
  • Received:2019-12-09 Revised:2020-03-05 Online:2020-11-22 Published:2020-11-20

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摘要： 针对高含盐氨氮废水，选择具有不同功能基团的树脂为载体，进行负载Cu2+改性制得载铜树脂并对其处理高含盐氨氮废水的性能进行研究。在筛选出最佳载铜树脂的基础上，研究pH及Na+浓度、树脂投加量、反应时间对载铜树脂处理高含盐氨氮废水效果的影响，通过对吸附氨氮前后的载铜树脂进行SEM和EDS表征分析并构建吸附动力学模型以进一步探究配位吸附的过程。结果表明，Cu2+可与螯合树脂D751稳定结合且在宽pH值下均表现出耐盐性和良好的氨氮吸附效果；在室温(25℃)、pH=11及Na+浓度4 g/L、树脂投加量8 g/L、反应时间60 min的条件下，D751载铜树脂对氨氮的去除率为34.8%。D751载铜树脂吸附氨氮后其表面出现明显的晶状结构物质，该物质可能为铜氨络合物。D751载铜树脂对高含盐氨氮的吸附符合准二级动力学模型。

关键词: 氨氮废水, 高含盐, 树脂, 铜离子, 配位吸附

Abstract: The ligand exchange adsorption method uses the ability of transition metal ions to form complexes. By supporting the transition metal on a certain adsorbent carrier, and then using the special complexation between the target pollutant and the transition metal, the target pollutant is adsorbed on the adsorbent. A ligand-loaded adsorbent was prepared by supporting Cu2+ with a resin as a carrier for the high-salt ammonia?nitrogen wastewater, and the ammonia nitrogen was selectively adsorbed onto the resin by the coordination of Cu2+ and ammonia nitrogen. Ammonia nitrogen is adsorbed to the resin in two ways: one is through the combination of NH4+ and OH? to generate NH3, which is coordinated with Cu2+on the resin; the other is that NH3 reacts directly with Cu2+ on the resin, so that ammonia nitrogen can be adsorbed. In this work, resins with different functional groups were selected as supports, modified with Cu2+, and their performance in treating high-salt ammonia nitrogen wastewater was studied. On the basis of selecting the best copper resin, the effects of pH, Na+ concentration, resin dosage and reaction time on the adsorption of ammonia nitrogen by copper resin were studied. In order to further explore the process of coordination adsorption, SEM, EDS and adsorption kinetics model were used to characterize the copper resin before and after ammonia nitrogen adsorption. The results showed that Cu2+ could combine with chelating resin D751 stably and exhibited salt tolerance and good adsorption effect of ammonia?nitrogen under wide pH value. Under the conditions of room temperature (25℃), pH=11, Na+ concentration of 4 g/L, resin dosage of 8 g/L, reaction time 60 min, the removal rate of ammonia?nitrogen by D751 copper-loaded resin was 34.8%. After adsorption of ammonia nitrogen by D751 copper resin, crystal structure substance appeared on its surface, which may be copper ammonia complex. In addition, the adsorption kinetics of D751 copper resin for ammonia nitrogen containing high saline was in good agreement with quasi-second-order kinetic model.

Key words: ammonia nitrogen wastewater, high salt content, resin, copper ion, coordination adsorption