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过程工程学报 ›› 2024, Vol. 24 ›› Issue (5): 599-608.DOI: 10.12034/j.issn.1009-606X.223252

• 研究论文 • 上一篇    下一篇

空气过滤用静电纺纳米纤维膜的制备及性能研究

程思敏1, 钱付平2*, 朱晨2, 陈路敏2, 董伟1, 仲怀玉2   

  1. 1. 安徽工业大学建筑工程学院,安徽 马鞍山 243032 2. 安徽工业大学能源与环境学院,安徽 马鞍山 243032
  • 收稿日期:2023-09-15 修回日期:2023-11-09 出版日期:2024-05-28 发布日期:2024-05-28
  • 通讯作者: 钱付平 fpingqian@163.com

Study on preparation and properties of electrospinning nanofiber membrane for air filtration

Simin CHENG1,  Fuping QIAN2*,  Chen ZHU2,  Lumin CHEN2,  Wei DONG1,  Huaiyu ZHONG2   

  1. 1. School of Civil Engineering and Architecture, Anhui University of Technology, Ma'anshan, Anhui 243032, China 2. School of Energy and Environment, Anhui University of Technology, Ma'anshan, Anhui 243032, China
  • Received:2023-09-15 Revised:2023-11-09 Online:2024-05-28 Published:2024-05-28
  • Contact: QIAN Fu-Ping fpingqian@163.com

摘要: 为了开发高效低阻的空气过滤用纤维膜,采用静电纺丝的方法制备了聚丙烯腈(PAN)静电纺纳米纤维膜。通过改变PAN浓度及静电纺丝时长,得到了不同形貌及过滤性能的静电纺纳米纤维膜。结合场发射扫描电子显微镜等表征方式和过滤性能测试台对静电纺纳米纤维膜形貌及过滤性能进行测试与分析,获得性能最优的PAN静电纺纳米纤维膜的制备参数如下:PAN浓度为9wt%,静电纺丝时长为5.0 h。此条件下制备的静电纺纳米纤维膜厚度为0.0240 mm,平均纤维直径为396 nm,PM2.5过滤效率为99.99%,过滤压降为67 Pa,品质因子最高,为0.137 Pa-1。

关键词: 静电纺丝, 纳米纤维膜, 空气过滤, PM2.5

Abstract: It has been proved by long-term practice that because the source of atmospheric aerosol particles is very wide, small size, the composition is very complex, the harm to the environment and human health is very serious. Although the government has taken a series of effective measures to control the pollution sources, it still takes a long time to completely solve the PM2.5 pollution problem. If the public wants to reduce the harm caused by particulate matter, specific measures must be taken to conduct individual protection and indoor air purification. At present, the simplest and most effective method for individual protection and indoor air purification is to filter the particles in the air through fiber filtration materials, thus reducing their content in the air. However, traditional fiber filtration materials have the disadvantages of low filtration efficiency, high filtration pressure drop and high energy consumption in the process of use. Meanwhile, filtration fibers with high filtration efficiency are often accompanied by higher filtration resistance. In order to develop high efficiency and low resistance fiber membrane for air filtration, polyacrylonitrile (PAN) electrospinning nanofibers were prepared by electrospinning. In the preparation process, the mass fraction of PAN and the duration of electrospinning were changed, and the electrospinning nanofiber films with different morphologies and filtration properties were obtained. The morphologies and filtration properties of electrostatic spinning nanofibers were tested and analyzed by field emission scanning electron microscopy and filtration test platform, and the preparation parameters of the best performance PAN electrostatic spinning nanofiber membranes were obtained with PAN mass fraction of 9wt%, electrospinning time of 5.0 h. Under the optimum condition, the film thickness of electrospinning nanofibers was 0.0240 mm, the average fiber diameter was 396 nm, the PM2.5 filtration efficiency was 99.99%, the filtration pressure drop was 67 Pa, and the highest quality factor was 0.137 Pa-1.

Key words: electrospinning, nanofiber membrane, air filtration, PM2.5