In the gas-solid flow, fluid and particle usually aggregate to form dense-phase and dilute-phase respectively, resulting in unbalanced mass transfer and reaction rates between the dense- and dilute-phase. The unbalance of dilute- and dense-phase reduces the overall efficiency of the reactor. To solve this problem, a hollow catalyst particle with pores structure is designed. It is aimed to enhance the overall efficiency of fluidized reactors by improving the mass transfer rate between the dense- and dilute-phase. Dense- and dilute-phase are widely distributed during fluidization processes, which can be respectively described by the cluster system and single particle system. In these two phases, the flow, reaction process and mass transfer process of hollow porous particles are studied by numerical simulation, and compared with the solid spherical particle system at the same fluidization condition. Then, the frequency of particle clusters formation and breakage is studied under various fluidization conditions. The time scale is analyzed to measure the possibility of gas transport in the fluidization process. It is found that the time-scales of the mass transfer, the reaction, and the movements of particles between the dilute- and dense-phase could be at the same order for some fluidization conditions. Thus, hollow porous catalyst particle can store the reacting material in the dilute-phase efficiently. When moving to the dense phase, the particle would release the reacting material to provide additional material for the dense-phase reaction. When the reaction is faster than the mass transfer, the overall reaction rate of the hollow porous catalyst system is 26.92%~29.55% higher than that of the solid spherical catalyst system at the studied conditions. It could be predicted that this hollow porous catalyst would be capable to improve the overall reaction efficiency of large gas-solid fluidized bed reactors due to wider distributions of the dilute- and dense-phase.
The energy consumption of electric water heater in China has a large proportion of total energy consumption. Therefore, it is of great significance to optimize the energy consumption process of electric water heater. The phase change materials (PCM) have the characteristics of high energy storage density and approximately constant temperature in the process of phase transition. In addition, the thermal conductivity of phase change materials can be enhanced by adding nanometer materials such as graphite. Therefore, it has obvious advantages in heat energy storage and utilization of phase change materials. So, the phase change energy storage technology can be applied to electric water heater to adjust the energy storage process and the goal of "peak shifting" also can be achieved. In this work, the energy storage characteristic of energy storage water heater with phase change material were researched employing numerical simulation method. Four different structural models were established and the influent of inlet and outlet piping construction, electric heating tube arrangement, insulation structure on flow and heat transfer characteristics of water in water heater were discussed. And the influence of energy storage layer thickness on energy storage of electric water heater were researched. The results showed that, compared with the vertical heating tube, the water temperature distribution of horizontal heating tube was more uniform during heating process, and the heating efficiency was improved by about 2.2%. When the inlet tube diameter increased to 1.5 times, the output status of hot water can be excellent improved, and the hot water output efficiency can be increased 17.9%. The addition of phase change materials can increase the water temperature by 10.6% under the condition of same heat preservation time (36 h). The results of this study can provide data support for structural optimization of electric water heater and application of phase change energy storage technology.