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›› 2014, Vol. 14 ›› Issue (2): 350-353.

• 材料工程专栏 • 上一篇    下一篇

水热法制备钐掺杂氧化锌及其对二甲胺气敏性能

宋金玲 任文强 包双峰 张胤 郭冠铭 蔡颖   

  1. 内蒙古科技大学稀土学院 内蒙古科技大学材料与冶金学院 内蒙古中煤蒙大新能源化工有限公司 内蒙古科技大学材料与冶金学院 内蒙古科技大学稀土学院 内蒙古科技大学稀土学院
  • 收稿日期:2014-04-22 修回日期:1900-01-01 出版日期:2014-04-20 发布日期:2014-04-20
  • 通讯作者: 宋金玲

Synthesis of Samarium-doped ZnO by Hydrothermal Method and Its Gas Sensing Properties towards Dimethylamine

SONG Jin-ling REN Wen-qiang BAO Shuang-feng ZHANG Yin GUO Guan-ming CAI Ying   

  1. School of Rare Earth, Inner Mongolia University of Science and Technology School of Material and Metallurgy, Inner Mongolia University of Science and Technology Inner Mongolia China-coal Mengda New Energy Chemical Industry CO. LTD Material and Metallurgical School, Inner Mongolia University of Science & Technology School of Rare Earth, Inner Mongolia University of Science and Technology School of Rare Earth, Inner Mongolia University of Science and Technology
  • Received:2014-04-22 Revised:1900-01-01 Online:2014-04-20 Published:2014-04-20
  • Contact: SONG Jin-ling

摘要: 采用水热法在不加任何助剂的情况下制备了六方纤锌矿ZnO及掺杂钐的ZnO (ZnO:Sm)粉体材料. 气敏测试结果显示,ZnO:Sm材料对二甲胺具有较高的灵敏度,随着二甲胺浓度增加,灵敏度呈现线性增加,当二甲胺气体的浓度为1.00′10-4时该气体传感器的检测灵敏度可达到63.97. 在三甲胺气氛中,ZnO:Sm对二甲胺具有优异的选择性,对二甲胺的响应时间为6 s,恢复时间为19 s.

关键词: ZnO, 钐掺杂, 气敏性能, 二甲胺, 三甲胺, 水热法

Abstract: The hexagonal wurtzite ZnO powder and samarium-doped ZnO powder (ZnO:Sm) were prepared by environment-friendly hydrothermal method without using any assisting agents. The gas sensing results show that the ZnO:Sm material exhibits better sensitivity towards dimethylamine. Its sensitivity increases with increasing of dimethylamine concentration. When the concentration of dimethylamine is 1.00′10-4, the sensitivity reaches 63.97. Moreover, in the atmosphere of trimethylamine, the sensitivity of ZnO:Sm towards dimethylamine exhibits excellent selectivity. The response time is about 6 s, and the recovery time about 19 s.

Key words: ZnO, samarium doping, gas sensing property, dimethylamine, trimethylamine, hydrothermal method

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