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过程工程学报 ›› 2022, Vol. 22 ›› Issue (1): 1-13.DOI: 10.12034/j.issn.1009-606X.220436

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选矿废水中残留黄药光催化处理及降解效率改进方式研究进展

梁锐1， 李明阳1,2,3*， 高翔鹏1， 于先坤4， 童雄3， 龙红明2   

  1. 1. 安徽工业大学冶金工程学院，安徽 马鞍山 243032 2. 安徽工业大学冶金减排与资源综合利用教育部重点实验室，安徽 马鞍山 243032 3. 昆明理工大学国土资源工程学院，云南 昆明 650093 4. 华唯金属矿产资源高效循环利用国家工程研究中心有限公司，安徽 马鞍山 243000
  • 收稿日期:2020-12-31 修回日期:2021-03-24 出版日期:2022-01-28 发布日期:2022-01-28
  • 通讯作者: 李明阳 my.l@outlook.com
  • 作者简介:梁锐(1999-)，男，安徽省淮南市人，资源循环科学与工程专业，E-mail: 1484301077@qq.com；李明阳，通讯联系人，E-mail: my.l@outlook.com.

Research progress on photocatalytic treatment of residual xanthate in mineral processing wastewater and improvement of degradation efficiency

Rui LIANG1,  Mingyang LI1,2,3*,  Xiangpeng GAO1,  Xiankun YU4,  Xiong TONG3,  Hongming LONG2   

  1. 1. School of Metallurgical Engineering, Anhui University of Technology, Ma'anshan, Anhui 243032, China 2. Key Laboratory of Metallurgical Emission Reduction & Resources Recycling, Ministry of Education, Anhui University of Technology, Ma'anshan, Anhui 243032, China 3. Faculty of Land and Resources Engineering, Kunming University of Science and Technology, Kunming, Yunnan 650093, China 4. National Engineering Research Center of Huawei High Efficiency Cyclic Utilization of Metal Mineral Resources, Ma'anshan, Anhui 243000, China
  • Received:2020-12-31 Revised:2021-03-24 Online:2022-01-28 Published:2022-01-28

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摘要： 光催化方法降解选矿废水中黄药是一种环境友好型的选矿废水处理工艺，具有操作简单方便、适用范围广、反应条件温和、无二次污染等优点。本工作以黄药为光催化降解对象，综述了近年来相关催化剂的研究进展，主要介绍了光催化剂的研究概况，根据光催化剂材料的差异及其改性方式的不同分类进行说明，其次基于影响光催化降解率的因素总结提出了改善方法，同时对光催化降解黄药的催化剂的设计及工艺开发进行了展望。

关键词: 光催化, 黄药, 降解, 改性, 降解效率

Abstract: Degrading the residual xanthate efficiently, environmentally, and economically in the mineral processing wastewater is a major problem needing to be solved urgently in the process of building a green mine. Photocatalytic degradation of xanthate in flotation wastewater is an environmentally friendly wastewater treatment process. It has many advantages, such as simple and convenient operation, wide application range, mild reaction conditions, free secondary pollution, etc. This work focuses on the application of photocatalytic degradation methods and reviews the research progress of photocatalysts of xanthate in recent years. It mainly introduces the research overview of photocatalysts according to the different classifications of photo-catalytic materials and their modification methods, and then explores the reaction mechanism and related influencing factors of photocatalytic degradation of xanthate. Moreover, improvement methods based on the factors affecting the degradation rate of photocatalysts are proposed. In the end, the design and process development of catalysts for photocatalytic degradation of xanthate were prospected. The photocatalytic materials currently used in the degradation of xanthate are mostly derived from metal semiconductors, including titanium, bismuth, zinc, copper, tungsten, iron-based compounds, and their modified substances, as well as non-metal semiconductor g-C3N4 and HAP-based photocatalyst. The ultimate goal of studying photocatalytic technology is to treat pollutants efficiently and environmentally. Therefore, how to improve the degradation efficiency is the core issue of the study. The existing literature mainly uses degradation conditions and photocatalysts to determine the factors affecting degradation efficiency and proposes targeted improvements. In addition, to make up for the shortcomings of a single photocatalyst, a combined process will be adopted to maximize the photocatalytic degradation efficiency.

Key words: photocatalysts, xanthate, mineral processing wastewater, chemical degradation, modification