碳酸锂的制备及其纯化过程的研究进展

doi:10.12034/j.issn.1009-606X.217234

过程工程学报 ›› 2018, Vol. 18 ›› Issue (1): 20-28.DOI: 10.12034/j.issn.1009-606X.217234

碳酸锂的制备及其纯化过程的研究进展

赵春龙^1,2，孙峙^2*，郑晓洪²，高文芳²，张延玲¹，林晓²

1. 北京科技大学钢铁冶金新技术国家重点实验室，北京 100083； 2. 中国科学院过程工程研究所环境技术与工程研究部，绿色过程与工程重点实验室，北京市过程污染控制工程技术研究中心，北京 100190

收稿日期:2017-05-09 修回日期:2017-06-06 出版日期:2018-02-22 发布日期:2018-01-29
通讯作者: 孙峙 sunzhi@ipe.ac.cn
基金资助:
国家科技支撑计划资助;中国科学院“率先行动”百人计划资助;国家自然科学基金：Cr的存在价态对熔渣基础物性及渣金两相分配行为的影响机理

Research Progress of Lithium Carbonate Preparation and Purification Process

Chunlong ZHAO^1,2, Zhi SUN^2*, Xiaohong ZHENG², Wenfang GAO², Yanling ZHANG¹, Xiao LIN²

1. State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083, China; 2. Beijing Engineering Research Center of Process Pollution Control, Key Laboratory of Green Process and Engineering, Division of Environment Technology and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

Received:2017-05-09 Revised:2017-06-06 Online:2018-02-22 Published:2018-01-29

摘要/Abstract

摘要： 近年来，随着锂离子电池的广泛应用及动力汽车产业的兴起，锂的需求量逐年增加. 碳酸锂作为一种最重要的基础锂盐，在锂离子电池中广泛应用，主要用于合成锂离子电池正极材料. 目前，高纯碳酸锂主要通过从矿石提锂浸出液或盐湖卤水中经过纯化工艺制备. 纯化方法主要包括碳化法、苛化法、电解法、碳酸锂重结晶法及离子交换法等. 但碳酸锂制备和纯化过程中存在诸多问题，如锂钠的深度分离、高纯碳酸锂的制备等. 本工作对碳酸锂制备及纯化方法进行综述，指出了碳酸锂制备及纯化过程中存在的主要问题及未来的发展方向.

关键词: 锂, 盐湖卤水, 碳酸锂, 纯化, 高纯碳酸锂

Abstract: With the extensive application of lithium-ion batteries and the rise of electric vehicle industrial in recent years, the demand of lithium is increase year by year. Lithium carbonate as one of the most important basic lithium salt, widely used in lithium-ion batteries, mainly used to synthesize lithium-ion battery cathode material. Currently, the preparation of high purity lithium carbonate is mainly through extracting lithium from lithium ore and salt lake brine, and then through purification process. The purification methods mainly including carbonization, custicization, electrolysis, lithium carbonate recrystallization and ion exchange, etc. However, there are many problems in the preparation and purification of lithium carbonate, such as deep separate lithium and sodium, preparation of high purity lithium carbonate etc. This paper reviews the preparation and purification ways of lithium carbonate, the exisiting problems and prospects for preparation and purification lithium carbonate are proposed.

Key words: lithium, salt lake brine, lithium carbonate, purification, high purity lithium carbonate

赵春龙孙峙郑晓洪高文芳张延玲林晓. 碳酸锂的制备及其纯化过程的研究进展[J]. 过程工程学报, 2018, 18(1): 20-28.

Chunlong ZHAO Zhi SUN Xiaohong ZHENG Wenfang GAO Yanling ZHANG Xiao LIN. Research Progress of Lithium Carbonate Preparation and Purification Process[J]. Chin. J. Process Eng., 2018, 18(1): 20-28.

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碳酸锂的制备及其纯化过程的研究进展

Research Progress of Lithium Carbonate Preparation and Purification Process

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