烟煤固体热载体低温快速热解实验研究

›› 2010, Vol. 10 ›› Issue (3): 530-535.

烟煤固体热载体低温快速热解实验研究

张梦蝶王泽张喜文王立昌林伟刚宋文立

中国科学院过程工程研究所多相复杂系统国家重点实验室中国科学院过程工程研究所多相复杂系统国家重点实验室中国电工设备总公司中国电工设备总公司中国科学院过程工程研究所多相反应开放实验室中国科学院过程工程研究所多相反应实验室

收稿日期:2010-04-06 修回日期:2010-05-14 出版日期:2010-06-20 发布日期:2010-06-20
通讯作者: 张梦蝶

Experimental Study on Fast Pyrolysis of Bituminous Coals by Solid Heat Carrier at Low Temperature

ZHANG Meng-die WANG Ze ZHANG Xi-wen WANG Li-chang LIN Wei-gang SONG Wen-li

State Key Laboratory of Multi-phase Complex System, Institute of Process Engineering, CAS State Key Laboratory of Multi-phase Complex System, Institute of Process Engineering, CAS China National Electric Equipment Corporation China National Electric Equipment Corporation Multi-phase Reaction Laboratory, Institute of Process Engineering Chinese Academic of Science Institute of Process Engineering, CAS

Received:2010-04-06 Revised:2010-05-14 Online:2010-06-20 Published:2010-06-20
Contact: ZHANG Meng-die

摘要/Abstract

摘要： 以连续式热解装置为实验平台，藁城和府谷煤为原料，石英砂为热载体，考察了460~520℃范围内热解所得气、液产物收率、组成和性质的变化规律. 结果表明，在考察的温度范围内，提高热解温度，热解气、液产物收率增加，液体产物收率最高可达12%左右. 热解温度对热解产物中不凝气组成影响显著，热解煤气热值高达25 MJ/Nm3以上. 焦油组分中酚衍生物含量最高，稠环烃、芳香烃、链烃组分的含量也较高，酚含量随热解温度增高有所降低，而芳烃含量则显著提高. 根据实验结果提出了酚-芳烃转化的可能路径.

关键词: 低温, 快速热解, 煤气, 焦油

Abstract: The pyrolysis of Gaocheng and Fugu coals in the temperature range from 460 to 520℃, heated by solid heat carrier of quartz sand, was investigated in a continuous pyrolytic apparatus. The yields, composition and characteristics of gas and liquid products were analyzed. The results show that within the temperature range, the yields of gas and liquid increase with increasing pyrolytic temperature, and the maximum liquid yield is about 12%. The gas composition obviously varies with pyrolytic temperature, and the heating value of coal gas is above 25 MJ/m3. The tar is in abundance of phenol derivatives, polycyclic aromatic hydrocarbons, benzene derivatives, and chain hydrocarbons are also found at higher content. The content of benzene derivatives increases with increasing temperature, but the content of phenols decreases with it. Based on the results, a simplified reaction route from phenol derivatives to aromatics has been proposed.

Key words: low temperature, fast pyrolysis, coal gas, tar

中图分类号:

TQ523.6

张梦蝶王泽张喜文王立昌林伟刚宋文立. 烟煤固体热载体低温快速热解实验研究[J]. , 2010, 10(3): 530-535.

ZHANG Meng-die WANG Ze ZHANG Xi-wen WANG Li-chang LIN Wei-gang SONG Wen-li. Experimental Study on Fast Pyrolysis of Bituminous Coals by Solid Heat Carrier at Low Temperature[J]. , 2010, 10(3): 530-535.

[1]	徐家明皇甫林史玉婷郭洪范高士秋李长明余剑. 低温烟气脱硝催化剂制备工艺及性能探究[J]. 过程工程学报, 2022, 22(7): 863-872.
[2]	林振浩李军业金志江钱锦远. LNG接收站用低温球阀阀座唇形密封圈接触特性分析[J]. 过程工程学报, 2022, 22(6): 819-827.
[3]	申展江志东张鹏飞张子瑜车海英马紫峰. 低温甲醇水重整制氢催化剂研究进展[J]. 过程工程学报, 2022, 22(5): 573-585.
[4]	张金星张样黄志甲祝立萍. 基于响应曲面法的高炉煤气CO₂吸收工艺参数优化[J]. 过程工程学报, 2021, 21(8): 985-992.
[5]	万琼任迎春赵志啸张新艳王文静郝婧羽黎璇鞠恺. 温度/pH双响应硝化菌凝胶球的制备及特性研究[J]. 过程工程学报, 2021, 21(11): 1346-1354.
[6]	向杰张松平张贵锋罗坚余蓉. 一步离子交换层析从Cohn组分V上清液中分离人血清白蛋白[J]. 过程工程学报, 2021, 21(1): 92-99.
[7]	王金德裴海鹏金保昇戴昕孙漪清. 高铝矾土改性对稻草热解与气化特性的影响[J]. 过程工程学报, 2019, 19(4): 783-791.
[8]	王力军徐凌锋杜晓成. 两段式气流床氧/煤比对干煤粉气化特性的影响[J]. 过程工程学报, 2019, 19(4): 836-844.
[9]	宁汝亮刘霄龙朱廷钰. 低温SCR脱硝催化剂研究进展[J]. 过程工程学报, 2019, 19(2): 223-234.
[10]	潘博王露雨王海军江松达万里强郝旭峰田杰黄发荣. 聚三唑酯树脂的合成及其性能[J]. 过程工程学报, 2019, 19(1): 181-188.
[11]	岳高伟曾春林郑新军霍留鹏. 基于DA模型的煤表面甲烷吸附线预测[J]. 过程工程学报, 2018, 18(5): 1045-1051.
[12]	尹寿来朱宝忠孙运兰訾朝辉陈诚李国波徐天宇. Ce改性Fe₂O₃/AC催化剂低温SCR脱硝性能[J]. 过程工程学报, 2018, 18(3): 509-516.
[13]	尹寿来朱宝忠孙运兰操政陈光江汝清徐天宇刘锋. Fe2O3/AC催化剂的低温选择性催化还原脱硝性能[J]. 过程工程学报, 2018, 18(2): 330-336.
[14]	赵渊黄黎明马风云钟梅. 溶胀对新疆淖毛湖煤样结构组成及热解性能的影响[J]. 过程工程学报, 2018, 18(1): 218-224.
[15]	曾红刘平乐张喻升李长明余剑许光文高士秋. 表面涂覆型低温脱硝催化剂的开发与中试应用[J]. 过程工程学报, 2017, 17(6): 1208-1216.